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Chapter 1: Q15CP (page 20)

Explain why changes in both enthalpy and entropy determine the spontaneity of a process.

Short Answer

Expert verified

Bothenthalpy and entropy determines the spontaneity of the process.

Step by step solution

01

Introduction

A reaction is said to be spontaneous if it occurs on its own without the aid of any external accelerating factor, and this is known as spontaneity of reaction, which is linked to the change in the reaction's Gibbs free energy.

02

Change in Gibbs free energy

The reaction's spontaneity is determined by the change in Gibbs free energy. The reaction is said to be spontaneous if the change inGibbs free energy is negative,and non-spontaneous if the change is positive.

03

Change inenthalpy and entropy

The Gibbs free energy is also influenced by the system's enthalpy and entropy. The Gibbs free energy of the reaction changes as the system's enthalpy and entropyfluctuate, which has an impact on the reaction's spontaneity.

Therefore, the changes in the enthalpy and entropy determines the spontaneityof the process.

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Most popular questions from this chapter

Explain why complementarity would have been necessary for the development of self-replicating molecules

ΔG°′ for the isomerization reaction

glucose-1-phosphate (G1P) →glucose-6-phosphate (G6P)

is −7.1 kJ · mol−1. Calculate the equilibrium ratio of [G1P] to [G6P] at 25°C.

Why is evolutionary change constrained by its past but impossible to predict?

(a) Which has greater entropy, liquid water at 0°Cor ice at0°C?
(b) How does the entropy of ice at−5°C differ, if at all, from its
entropyat−50°C?

Can a process occur if the entropy of the system decreases and the enthalpy increases?
See all solutions

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