The bacterium that is capable of performing nitrogen fixation is

Rhizobium bacteria play a critical role in the natural nitrogen cycle, specifically through an eco-friendly process known as nitrogen fixation. These microscopic organisms inhabit soil environments where they uniquely thrive by partnering with leguminous plants (the pea family).
There exists a diverse array of Rhizobium species, each adapted to form partnerships with different plant hosts. During the initial stages of this relationship, Rhizobium bacteria infect the roots of legume plants, leading to the formation of root nodules. These nodules, which might be imagined as small growths on the roots, become the factories where nitrogen fixation occurs.

Adaptive Advantages

Rhizobium bacteria possess specific genetic attributes enabling them to sense chemical signals from the legume roots, initiating the infection process and eventual nodule formation. Furthermore, these bacteria are equipped to survive in oxygen-poor conditions within the nodules, a crucial trait since the enzyme that catalyzes nitrogen fixation is oxygen-sensitive.

In the world of biology, a symbiotic relationship is a close, long-term interaction between two different species, and the partnership between Rhizobium bacteria and legumes is a classic example. This particular type of symbiosis is mutually beneficial, technically termed mutualism.
Here's how the mutualism plays out: the legume plants provide Rhizobium with carbohydrates derived from photosynthesis, essentially the plant's sugar. In exchange, Rhizobium bacteria offer the plants a much-needed nutrient, nitrogen, but not in its gaseous form. These bacteria convert atmospheric nitrogen into a form plants can absorb and use for growth—a process pivotal for agricultural productivity.

Importance for Agriculture

This natural exchange is so valuable that it reduces the need for artificial nitrogen fertilizers, which can be harmful to the environment. Farmers often rotate crops and plant legumes like peas, beans, and clover to naturally enrich the soil with nitrogen, courtesy of the Rhizobium's activity. This practice illustrates the significance of understanding and harnessing symbiotic relationships for sustainable agriculture.

At the core of nitrogen fixation lies the nitrogenase enzyme, a biological catalyst that makes possible the conversion of atmospheric nitrogen (N₂) – which most organisms cannot use – into ammonia (NH₃), a form that plants can readily assimilate.
Nitrogenase functions under quite remarkable conditions. It's highly sensitive to oxygen, which normally deactivates the enzyme's capabilities. This requirement poses a challenge because the Earth's atmosphere is rich in oxygen. However, the Rhizobium bacteria overcome this by residing within the anaerobic environment of root nodules in legumes. Here, the nitrogenase enzyme can work efficiently, shielded from oxygen, to break the incredibly strong triple bond of the nitrogen molecules.
The reaction catalyzed by nitrogenase is energy-intensive, requiring a substantial input of ATP (adenosine triphosphate, the energy currency of cells) and a constant source of electrons. The simplistic reaction formula (N₂ + 8 H⁺ + 8 e⁻ → 2 NH₃ + H₂)outlines how the enzyme uses hydrogen ions (protons) and electrons to reduce nitrogen to ammonia. The subsequent uptake of this ammonia by plants is fundamental to their growth, as it's a building block for amino acids and nucleic acids.