Inversion temperature is defined as the temperature above which a gas gets warm up and below which, the gas become cooler, when expanded adiabatically. Boyle temperature for a gas is \(20^{\circ} \mathrm{C}\). What will happen to the gas if it is adiabatically expanded at \(50^{\circ} \mathrm{C}\) ? (a) Heating (b) Cooling (c) Neither heating nor cooling (d) First cooling then heating

Short Answer

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Heating

Step by step solution

01

Understand the Definitions

Firstly, comprehend the concepts of inversion and Boyle temperature. Inversion temperature is the threshold above which a gas will heat up when expanded adiabatically, and below which it will cool down. Boyle temperature is a specific case of inversion temperature where the internal energy of a gas does not change with volume at constant temperature for an ideal gas.
02

Compare Given Temperatures

Next, compare the given temperature at which the gas is expanded (\(50^{\text{o}}C\) with the Boyle temperature (\(20^{\text{o}}C\)). Since the temperature at which the gas is expanded is higher than the Boyle temperature, it is higher than the inversion temperature as well.
03

Determine the Gas Behavior

According to the definition of inversion temperature, because the gas is expanded at a temperature above the inversion (Boyle) temperature, the gas will heat up when expanded adiabatically.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Adiabatic Expansion
Understanding adiabatic expansion is key to grasping many phenomena in thermodynamics. It refers to a process in which a gas expands without exchanging heat with its environment. This might initially sound puzzling: How can the gas's volume increase without a heat transfer?

When a gas undergoes adiabatic expansion, its particles do work to push against the external pressure, and as a result, their kinetic energy decreases. If a gas expands at a temperature above its inversion temperature, it absorbs energy from the work done during expansion and heats up. On the other hand, below the inversion temperature, the gas would cool down as it does work on its surroundings.

This behavior ties directly into our problem, where we consider a gas initially at a higher temperature than its Boyle temperature undergoing expansion.
Boyle Temperature
The Boyle temperature is a unique point for a gas where its pressure is directly proportional to volume, following Boyle's Law, but only at this specific temperature. More formally, it marks the condition under which a real gas behaves like an ideal gas, and the intermolecular forces are effectively 'cancelled out' for changes in volume at constant temperature.

In the context of our problem, knowing the Boyle temperature of a gas helps us determine how it will behave when adiabatically expanded. If expanded at a temperature above the Boyle temperature (which we established is equal to the gas's inversion temperature), the gas will experience heating, which in our case happens at the higher temperature of 50 degrees Celsius.
Gas Laws
The behavior of gases under various conditions of temperature, pressure, and volume is governed by gas laws. These laws are crucial for understanding the fundamentals of thermodynamics and how gases react to different physical situations.

Key gas laws include Boyle's Law, which states that pressure inversely varies with volume at constant temperature; Charles's Law, connecting volume and temperature at constant pressure; and Gay-Lussac's Law, relating pressure and temperature at constant volume. Each of these describes how one particular property of a gas will change, holding the others steady.

In our scenario, Boyle's Law is of particular importance as it lays the foundation for understanding the Boyle temperature concept. As gas laws are often idealized, discussing the inversion temperature further provides insight into how real gases deviate from these ideal relationships.
Thermodynamics
Thermodynamics is the branch of physics that deals with the relationships between heat and other forms of energy. In our exercise, thermodynamics helps us predict the outcome of adiabatic processes among other heat-related transformations.

Four main laws of thermodynamics lay the foundation for energy and heat transfer analysis. The first law, essentially the law of energy conservation, states that energy can neither be created nor destroyed, only transformed. This law is particularly relevant in adiabatic processes, as the internal energy change of a gas is equal to the work done on or by the gas since no heat is exchanged.

Our study of inversion temperature dips into the heart of thermodynamics, combining concepts of energy, work, and heat transfer, to explain why a gas would heat up or cool down when adiabatically expanded at different temperatures.

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Most popular questions from this chapter

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