The word standard in molar enthalpy change implies (a) temperature \(298 \mathrm{~K}\) and pressure 1 atm (b) any temperature and pressure 1 atm (c) any temperature and pressure 1 bar (d) any temperature and pressure

Short Answer

Expert verified
The word 'standard' in molar enthalpy change implies a temperature of 298 K and pressure 1 atm, which is option (a).

Step by step solution

01

- Understanding the Concept of 'Standard' in Chemistry

The term 'standard' when used in chemistry, particularly in the context of thermodynamic processes like molar enthalpy change, refers to a set of default conditions that are commonly adopted for measurements. These conditions typically include a specific temperature and pressure.
02

- Identifying the Standard Conditions

The standard temperature is usually set at 298 K, which is approximately 25 degrees Celsius. The standard pressure can be defined either as 1 atm (atmosphere) or very closely as 1 bar (100 kPa). However, for historical and conventional reasons, standard conditions specifically refer to 1 atm.
03

- Selecting the Correct Option

Based on the definitions of standard conditions in chemistry, we can now identify the correct option. The term 'standard' in the context of molar enthalpy change implies a temperature of 298 K and a pressure of 1 atm.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Thermodynamic Processes
Thermodynamics is a branch of physics that deals with the relationships between heat and other forms of energy. In the realm of chemistry, understanding thermodynamic processes is central to the study of how substances interact with energy. These processes can be viewed as a sequence of steps during which certain properties of a system, such as temperature, pressure, and volume, change from an initial state to a final state.

A key concept in thermodynamics is the system's ability to do work and transfer heat. When substances react chemically, they absorb or release energy in the form of heat, leading to a change in the system's enthalpy—a measure of the total heat content. The study of thermodynamic processes often involves calculations of energy changes during chemical reactions, helping scientists predict the direction of the reaction and the extent to which it will proceed under various conditions.
Standard Conditions in Chemistry
In chemistry, 'standard conditions' refer to a set of predefined conditions of pressure and temperature that are used to facilitate consistent and reliable measurements and comparisons of different chemical substances and reactions. The term can sometimes be a source of confusion, as different fields may define standard conditions differently.

For thermodynamic quantities like enthalpy, standard conditions typically mean a temperature of 298 K (which is equivalent to 25 degrees Celsius) and a pressure of exactly 1 atm (atmosphere). It's worth noting that although 1 bar (100 kPa) is very close to 1 atm, 1 atm is the accepted pressure for standard conditions in many thermodynamic contexts. Therefore, when you encounter the word 'standard' in chemistry, it is crucial to understand these specific conditions to properly interpret or conduct an experiment.
Molar Enthalpy
Molar enthalpy, an integral term in thermodynamics and chemistry, refers to the enthalpy change per mole of substance. It's an extensive property of a system, meaning its value is proportional to the amount of substance in the system. The standard molar enthalpy change, often represented as \( \Delta H_{m}^\circ \), provides information about the heat absorbed or released when one mole of a substance undergoes a chemical process under standard conditions.

The concept of molar enthalpy is used to quantify the energy involved in reactions, phase changes (such as melting or boiling), and formation or breaking of chemical bonds. This kind of data is highly valuable not only for predicting reaction behavior but also for practical applications, such as designing industrial processes and understanding environmental impacts of chemical reactions. Measuring enthalpy changes during reactions enables scientists to gauge the feasibility and efficiency of a chemical process.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

The standard enthalpies of formation of \(\mathrm{H}_{2} \mathrm{O}(\mathrm{l}), \mathrm{Li}^{+}(\mathrm{aq})\) and \(\mathrm{OH}^{-}(\mathrm{aq})\) are \(-285.8\), \(-278.5\) and \(-228.9 \mathrm{~kJ} / \mathrm{mol}\), respectively. The standard enthalpy change for the reaction is \(2 \mathrm{Li}(\mathrm{s})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \rightarrow 2 \mathrm{Li}^{+}(\mathrm{aq})+2 \mathrm{OH}^{-}(\mathrm{aq})\) \(+\mathrm{H}_{2}(\mathrm{~g})\) (a) \(+443.2 \mathrm{~kJ}\) (b) \(-443.2 \mathrm{~kJ}\) (c) \(-221.6 \mathrm{~kJ}\) (d) \(+221.6 \mathrm{~kJ}\)

Given two processes: (i) \(1 / 2 \mathrm{P}_{4}(\mathrm{~s})+3 \mathrm{Cl}_{2}(\mathrm{~g}) \rightarrow 2 \mathrm{PCl}_{3}(1) ; \Delta H\) \(=-635 \mathrm{~kJ}\) (ii) \(\mathrm{PCl}_{3}(\mathrm{l})+\mathrm{Cl}_{2}(\mathrm{~g}) \rightarrow \mathrm{PCl}_{5}(\mathrm{~s}) ; \Delta H\) \(=-137 \mathrm{~kJ}\) The value of \(\Delta_{\mathrm{f}} H\) of \(\mathrm{PCl}_{5}(\mathrm{~s})\) is (a) \(454.5 \mathrm{~kJ} \mathrm{~mol}^{-1}\) (b) \(-454.5 \mathrm{~kJ} \mathrm{~mol}^{-1}\) (c) \(-772 \mathrm{~kJ} \mathrm{~mol}^{-1}\) (d) \(-498 \mathrm{~kJ} \mathrm{~mol}^{-1}\)

Equal volumes of one molar hydrochloric acid and one molar sulphuric acid are neutralized completely by dilute \(\mathrm{NaOH}\) solution by which \(X\) and \(Y\) kcal of heat are liberated, respectively. Which of the following is true? (a) \(X=Y\) (b) \(2 X=Y\) (c) \(X=2 Y\) (d) none of these

A quantity that cannot be directly measured is (a) heat of formation of \(\mathrm{H}_{2} \mathrm{O}(\mathrm{l})\) (b) heat of formation of \(\mathrm{CH}_{4}(\mathrm{~g})\) (c) latent heat of fusion of ice (d) heat of combustion of ethyl alcohol

Tungsten carbide is very hard and is used to make cutting tools and rock drills. What is the enthalpy of formation (in \(\mathrm{kJ} / \mathrm{mol}\) ) of tungsten carbide? The enthalpy change for this reaction is difficult of measure directly, because the reaction occurs at \(1400^{\circ} \mathrm{C}\). However, the enthalpies of combustion of the elements and of tungsten carbide can be measured easily. \(2 \mathrm{~W}(\mathrm{~s})+3 \mathrm{O}_{2}(\mathrm{~g}) \rightarrow 2 \mathrm{WO}_{3}(\mathrm{~s}) ; \Delta H\) \(=-1680.6 \mathrm{~kJ}\) \(\mathrm{C}(\) graphite \()+\mathrm{O}_{2}(\mathrm{~g}) \rightarrow \mathrm{CO}_{2}(\mathrm{~g}) ; \quad \Delta H\) \(=-393.5 \mathrm{~kJ}\) \(2 \mathrm{WC}(\mathrm{s})+5 \mathrm{O}_{2}(\mathrm{~g}) \rightarrow 2 \mathrm{WO}_{3}(\mathrm{~s})+2 \mathrm{CO}_{2}(\mathrm{~g})\) \(\Delta H=-2391.6 \mathrm{~kJ}\) (a) \(-38.0\) (b) \(-76.0\) (c) \(-19.0\) (d) \(-1233.8\)

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free