Chapter 9: Problem 38
Packing fraction in \(\mathrm{BCC}\) lattice is (a) \(\frac{1}{6} \pi\) (b) \(\frac{\sqrt{2}}{6} \pi\) (c) \(\frac{\sqrt{3}}{8} \pi\) (d) \(\frac{\sqrt{3}}{2} \pi\)
Short Answer
Expert verified
The packing fraction in BCC lattice is \( \frac{\sqrt{3}}{8} \pi \)
Step by step solution
01
Understand Packing Fraction
Packing fraction is the fraction of volume in a crystal lattice that is occupied by the constituent particles. For a Body-Centered Cubic (BCC) lattice, it involves calculating the volume occupied by the spheres (atoms) in one unit cell and dividing it by the total volume of the unit cell.
02
Calculate Volume Occupied by Atoms in BCC Lattice
In a BCC lattice, there is one atom at each corner of the cube and one atom in the center. Each corner atom is shared by 8 adjacent unit cells, so only 1/8 of each corner atom is within one unit cell. Since there are 8 corners, this contributes one whole atom. The central atom is entirely within the unit cell. Therefore, the total number of atoms in a BCC unit cell is 2. The volume of one atom is \( \frac{4}{3} \pi r^3 \), so for two atoms, the volume is \( \frac{8}{3} \pi r^3 \) where r is the radius of an atom.
03
Calculate Total Volume of the Unit Cell
The body diagonal of the BCC unit cell is equal to \( 4r \) because the body diagonal passes through the center of one sphere, the whole diameter of the central sphere, and the center of the other sphere. Using the diagonal, we can express the side of the cube as \( a = \frac{\sqrt{3}}{2} \cdot 4r \). Thus, the total volume of the unit cell is \( a^3 = \left(\frac{\sqrt{3}}{2} \cdot 4r\right)^3 \) or \( \frac{3\sqrt{3}}{2} \pi r^3 \) after substituting the expression for a.
04
Find the Packing Fraction
Divide the volume occupied by the atoms by the total volume of the unit cell to find the packing fraction: \( \frac{\frac{8}{3} \pi r^3}{\left(\frac{\sqrt{3}}{2} \cdot 4r\right)^3} \) which simplifies to \( \frac{\sqrt{3}}{8} \pi \) after canceling out the common terms.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Crystal Lattice
In the realm of solid-state physics and materials science, a crystal lattice represents the highly ordered arrangement of atoms or molecules within a crystalline material. Each point in this lattice is known as a lattice point, indicating the position of a particle, which could be an atom, ion, or molecule.
It's essential to visualize the crystal lattice as a three-dimensional framework where repeating units, called unit cells, extend in all directions. This pattern gives the crystal its stability and unique properties. For example, the arrangement influences how light interacts with the crystal, its electrical conductivity, and its melting point.
When examining different materials, one often encounters various types of crystal lattices. These lattices are categorized based on their geometric configuration – cubic, tetragonal, orthorhombic, among others. Each type has its distinct packing and symmetry characteristics that influence the material's physical properties.
It's essential to visualize the crystal lattice as a three-dimensional framework where repeating units, called unit cells, extend in all directions. This pattern gives the crystal its stability and unique properties. For example, the arrangement influences how light interacts with the crystal, its electrical conductivity, and its melting point.
When examining different materials, one often encounters various types of crystal lattices. These lattices are categorized based on their geometric configuration – cubic, tetragonal, orthorhombic, among others. Each type has its distinct packing and symmetry characteristics that influence the material's physical properties.
Volume Calculation in Unit Cells
The volume of a unit cell is a fundamental concept to understand when delving into crystalline structures. It essentially represents the smallest volume that still retains the geometric and physical properties of the entire crystal.
To calculate the volume of a unit cell, one must determine the dimensions of the cell. Depending on the cell's geometric shape, this could involve measuring the lengths of its edges and possibly the angles between these edges. Once these measurements are obtained, a variety of geometric formulas can be used to calculate the total volume. For example, the volume of a cubic cell is simply the cube of the edge length.
Understanding the volume of a unit cell is critical in determining the density of the material, the packing efficiency of the atoms within the cell, and other important physical properties.
To calculate the volume of a unit cell, one must determine the dimensions of the cell. Depending on the cell's geometric shape, this could involve measuring the lengths of its edges and possibly the angles between these edges. Once these measurements are obtained, a variety of geometric formulas can be used to calculate the total volume. For example, the volume of a cubic cell is simply the cube of the edge length.
Understanding the volume of a unit cell is critical in determining the density of the material, the packing efficiency of the atoms within the cell, and other important physical properties.
Body-Centered Cubic Structure
The Body-Centered Cubic (BCC) structure is a type of crystal lattice configuration where atoms are located at each corner of a cube and a single atom is positioned at the very center of the cube. This arrangement is a common one found in metals such as iron at certain temperatures.
In a BCC lattice, the atoms at the corners are shared among eight adjacent unit cells. Therefore, each corner atom contributes only an eighth of their volume to any single cell. The central atom, on the other hand, belongs entirely to the unit cell it's situated in. Consequently, there are effectively two whole atoms per BCC unit cell.
The BCC structure's packing fraction, which measures how much of the unit cell's volume is occupied by atoms, is less than that of a face-centered cubic (FCC) structure but greater than a simple cubic structure. The BCC packing fraction is useful for understanding properties like the material's density and how many atoms can be packed into a given space in certain metals.
In a BCC lattice, the atoms at the corners are shared among eight adjacent unit cells. Therefore, each corner atom contributes only an eighth of their volume to any single cell. The central atom, on the other hand, belongs entirely to the unit cell it's situated in. Consequently, there are effectively two whole atoms per BCC unit cell.
The BCC structure's packing fraction, which measures how much of the unit cell's volume is occupied by atoms, is less than that of a face-centered cubic (FCC) structure but greater than a simple cubic structure. The BCC packing fraction is useful for understanding properties like the material's density and how many atoms can be packed into a given space in certain metals.