Calculate the heat change at $0°$. for each of the following. and indicate whether heat was absorbed/released:

a. calories to freeze$35\mathrm{g}$of water

h. joules to freeze$275\mathrm{g}$ of water

c. kilocalories to melt$140\mathrm{g}$ of ice

d. kilojoules to melt$5.00\mathrm{g}$ of ice

Calculate the heat change at $0°C$. for each of the following. and indicate whether heat was absorbed/released

(a)

The mass of water is $35g$and the heat of fusion of water in calorie per gram is$80cal/g$.Now, use the following formula to calculate the change in temperature:

Heat change $=$mass $\times$heat of fusion

$=35\mathrm{g}\times \frac{80\mathrm{cal}}{\mathrm{g}}$

$=2.8\times {10}^3\mathrm{cal}$

Therefore, the heat change is.$2.8\times {10}^3\mathrm{cal}$As a result, the heat was released during the freezing process.

(b)

The mass of water is$275g$and the heat of fusion of water in joule per gram is$334J/g$.

Now, use the following formula to calculate the change in temperature:

Heat changelocalid="1651760143986" $=$masslocalid="1651760149198" $\times$heat of fusion

$=275\mathrm{g}\times \frac{334\mathrm{J}}{\mathrm{g}}$

$=9.19\times {10}^4\mathrm{J}$

Therefore, the heat change$=9.19\times {10}^4\mathrm{J}$. As a result, the heat was released during the freezing process.

(c)

The mass of ice is $140g$and the heat of fusion of ice in calorie per gram is$80\mathrm{cal}/\mathrm{g}$.Now, use the following formula to calculate the change in temperature:

Heat change$=$mass $\times$heat of fusion

$=140\mathrm{g}\times \frac{80\mathrm{cal}}{\mathrm{g}}\times \frac{0.001\mathrm{kcal}}{1\mathrm{cal}}$

$=11.2\mathrm{kcal}$

Therefore, the heat change is$=11.2\mathrm{kcal}$As a result, the heat was absorbed during the melting process.

(d)

The mass of ice is $5.00\mathrm{g}$and the heat of fusion of ice in joule per gram is $334\mathrm{J}/\mathrm{g}.$Now, use the following formula to calculate the change in temperature:

Heat change $=$mass $\times$heat of fusion

$=5.00\mathrm{g}\times \frac{334\mathrm{J}}{\mathrm{g}}\times \frac{1\mathrm{kJ}}{1000\mathrm{J}}$

$=1.67\mathrm{kJ}$

Therefore, the heat change is $=1.67\mathrm{kJ}$. As a result, the heat was absorbed during the melting process.