The four substances \(\mathrm{HCl}, \mathrm{I}_{2}, \mathrm{HI}\), and
\(\mathrm{Cl}_{2}\) are mixed in a reaction vessel and allowed to reach
equilibrium in the reaction \(2
\mathrm{HCl}(\mathrm{g})+\mathrm{I}_{2}(\mathrm{~s}) \rightleftharpoons 2
\mathrm{HI}(\mathrm{g})+\mathrm{Cl}_{2}(\mathrm{~g})\). Certain changes (which
are specified in the first column in the following table) are then made to
this mixture. Considering each change separately, state the effec (increase,
decrease, or no change) that the change has on the original equilibrium value
of the quantity in the second column (or \(K\), if that is specified). The
temperature and volume are constant.
Change Quantity
(a) add \(\mathrm{HCl} \quad\) amount of HI
(b) add \(\mathrm{I}_{2} \quad\) amount of \(\mathrm{Cl}_{2}\)
(c) remove HI amount of \(\mathrm{Cl}_{2}\)
(d) remove \(\mathrm{Cl}_{2} \quad\) amount of \(\mathrm{HCl}\)
(e) add \(\mathrm{HCl} \quad K\)
(f) remove \(\mathrm{HCl}\) amount of \(\mathrm{I}_{2}\)
(g) add \(\mathrm{I}_{2} \quad \mathrm{~K}\)