Complete the following statements for the reaction \(6 \mathrm{Li}(\mathrm{s})+\mathrm{N}_{2}(\mathrm{~g}) \rightarrow 2 \mathrm{Li}_{3} \mathrm{~N}(\mathrm{~s})\). The rate of consumption of \(\mathrm{N}_{2}\) is _______ times the rate of formation of \(\mathrm{Li}_{3} \mathrm{~N}\). (b) The rate of formation of \(\mathrm{Li}_{3} \mathrm{~N}\) is _____times the rate of consumption of Li. (c) The rate of consumption of \(\mathrm{N}_{2}\) is ________ times the rate of consumption of Li.

Short Answer

Expert verified
The rate of consumption of \(\mathrm{N}_{2}\) is 0.5 times the rate of formation of \(\mathrm{Li}_{3} \mathrm{N}\). The rate of formation of \(\mathrm{Li}_{3} \mathrm{N}\) is 0.333 times the rate of consumption of Li. The rate of consumption of \(\mathrm{N}_{2}\) is 0.167 times the rate of consumption of Li.

Step by step solution

01

Understanding the Chemical Reaction

The balanced chemical equation given is: \[6\mathrm{Li}(\mathrm{s}) + \mathrm{N}_{2}(\mathrm{g}) \rightarrow 2\mathrm{Li}_{3}\mathrm{N}(\mathrm{s})\].This tells us that 6 moles of Lithium (Li) react with 1 mole of Nitrogen gas (\(\mathrm{N}_{2}\)) to form 2 moles of Lithium Nitride (\(\mathrm{Li}_{3}\mathrm{N}\)).
02

Determining the Rate of Consumption of \(\mathrm{N}_{2}\)

Since the balanced chemical equation shows that 1 mole of \(\mathrm{N}_{2}\) forms 2 moles of \(\mathrm{Li}_{3}\mathrm{N}\), the rate of consumption of \(\mathrm{N}_{2}\) is half the rate of formation of \(\mathrm{Li}_{3}\mathrm{N}\).
03

Determining the Rate of Formation of \(\mathrm{Li}_{3} \mathrm{N}\)

According to the stoichiometry of the reaction, 6 moles of Li are consumed to form 2 moles of \(\mathrm{Li}_{3}\mathrm{N}\). This means the rate of formation of \(\mathrm{Li}_{3}\mathrm{N}\) is one-third the rate of consumption of Li.
04

Determining the Rate Ratio of \(\mathrm{N}_{2}\) Consumption to Li Consumption

From the stoichiometric coefficients, we can see that 1 mole of \(\mathrm{N}_{2}\) reacts with 6 moles of Li. Therefore, the rate of consumption of \(\mathrm{N}_{2}\) is one-sixth the rate of consumption of Li.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Reaction Rates
Understanding the speed at which chemical reactions occur is crucial in various fields including manufacturing, environmental science, and biology. The rate of a chemical reaction indicates how quickly reactants are consumed and products are formed over time. For example, in the reaction \[6\mathrm{Li}(\mathrm{s}) + \mathrm{N}_{2}(\mathrm{g}) \rightarrow 2\mathrm{Li}_{3}\mathrm{N}(\mathrm{s})\],we analyze the reaction rates in terms of the disappearance of reactants (\(\mathrm{N}_{2}\)and \(\mathrm{Li}\)) and the appearance of the product (\(\mathrm{Li}_{3}\mathrm{N}\)).

For a balanced reaction, the rates are inversely proportional to the stoichiometric coefficients—this is known as the rate law. Thus, if \(\mathrm{N}_{2}\) is consumed at a certain rate, \(\mathrm{Li}_{3}\mathrm{N}\) will form at twice that rate because two moles of \(\mathrm{Li}_{3}\mathrm{N}\) form for each mole of \(\mathrm{N}_{2}\) consumed.

Understanding this relationship can help predict how changes in conditions (like temperature or catalysts) will affect the rate, allowing us to control and optimize reactions in industrial processes or even prevent unwanted reactions in the environment.
Chemical Equation Balancing
Balancing a chemical equation is akin to balancing a scale—it ensures that the mass and the number of atoms are conserved in a chemical reaction. When we balance an equation, such as \[6\mathrm{Li}(\mathrm{s}) + \mathrm{N}_{2}(\mathrm{g}) \rightarrow 2\mathrm{Li}_{3}\mathrm{N}(\mathrm{s})\],we are confirming that there are equal numbers of each type of atom on both sides of the reaction.

This balance is fundamental, as it reflects the law of conservation of mass. It also provides the basis for calculations in stoichiometry, as the coefficients (the numbers in front of the chemical formulas) represent the ratios of moles of each reactant and product involved in the reaction. As a result, the balanced equation guides us in predicting the quantities of reactants needed and products formed.

Precise balancing is essential for both laboratory work and industrial chemical production, ensuring that reactions occur completely and resources are not wasted.
Mole Concept
The mole concept is a bridge between the microscopic world of atoms and molecules and the macroscopic world we live in. A mole is Avogadro’s number (\(6.022 \times 10^{23}\)) of particles, which can be atoms, molecules, ions, or electrons. For instance, when the chemical equation \[6\mathrm{Li}(\mathrm{s}) + \mathrm{N}_{2}(\mathrm{g}) \rightarrow 2\mathrm{Li}_{3}\mathrm{N}(\mathrm{s})\]states that 6 moles of lithium react with 1 mole of nitrogen gas, it tells us that \(6 \times 6.022 \times 10^{23}\) atoms of lithium react with \(6.022 \times 10^{23}\) molecules of nitrogen gas.

The concept helps us quantify chemical reactions, as these mole ratios are used to calculate the mass of reactants and products. By understanding the mole, students can better grasp how macroscopic quantities of substances relate to the underlying chemical equations and reactions.

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Most popular questions from this chapter

The pre-equilibrium and the steady-state approximations are two different approaches to deriving a rate law from a proposed mechanism. For the following mechanism, determine the rate law (a) by the pre-equilibrium approximation and (b) by the steady-state approximation. (c) Under what conditions do the two methods give the same answer? (d) What will the rate laws become at high concentrations of \(\mathrm{Br}^{-}\)? $$ \begin{aligned} &\mathrm{CH}_{3} \mathrm{OH}+\mathrm{H}^{+} \rightleftharpoons \mathrm{CH}_{3} \mathrm{OH}_{2}^{+} \text {(fast equilibrium) } \\ &\mathrm{CH}_{3} \mathrm{OH}_{2}^{+}+\mathrm{Br}^{-} \longrightarrow \mathrm{CH}_{3} \mathrm{Br}+\mathrm{H}_{2} \mathrm{O} \text { (slow) } \end{aligned} $$

The mechanism proposed for the oxidation of iodide ion by the hypochlorite ion in aqueous solution is as follows: Step \(1 \mathrm{ClO}^{-}+\mathrm{H}_{2} \mathrm{O} \longrightarrow \mathrm{HClO}+\mathrm{OH}^{-}\)and its reverse (both fast, equilibrium) Step \(2 \mathrm{I}^{-}+\mathrm{HClO} \longrightarrow \mathrm{HIO}+\mathrm{Cl}^{-}\)(slow) Step \(3 \mathrm{HIO}+\mathrm{OH}^{-} \longrightarrow \mathrm{IO}^{-}+\mathrm{H}_{2} \mathrm{O}\) (fast) Write the rate law for the formation of HIO implied by this mechanism.

Complete the following statements relating to the production of ammonia by the Haber process, for which the overall reaction is \(\mathrm{N}_{2}(\mathrm{~g})+3 \mathrm{H}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{NH}_{3}(\mathrm{~g}) \cdot\) (a) The rate of consumption of \(\mathrm{N}_{2}\) is ______ times the rate of consumption of \(\mathrm{H}_{2}\). (b) The rate of formation of \(\mathrm{NH}_{3}\) is _____ times the _______times the rate of consumption of \(\mathrm{N}_{2}\).

When the rate of the reaction \(2 \mathrm{NO}(\mathrm{g})+\mathrm{O}_{2}(\mathrm{~g}) \rightarrow\) \(2 \mathrm{NO}_{2}(\mathrm{~g})\) was studied, the rate was found to double when the \(\mathrm{O}_{2}\) concentration alone was doubled but to quadruple when the NO concentration alone was doubled. Which of the following mechanisms accounts for these observations? Explain your reasoning. (a) Step \(1 \mathrm{NO}+\mathrm{O}_{2} \longrightarrow \mathrm{NO}_{3}\) and its reverse (both fast, equilibrium) Step \(2 \mathrm{NO}+\mathrm{NO}_{3} \rightarrow \mathrm{NO}_{2}+\mathrm{NO}_{2}\) (slow) (b) Step \(1 \mathrm{NO}+\mathrm{NO} \rightarrow \mathrm{N}_{2} \mathrm{O}_{2}\) (slow) Step \(2 \mathrm{O}_{2}+\mathrm{N}_{2} \mathrm{O}_{2} \rightarrow \mathrm{N}_{2} \mathrm{O}_{4}\) (fast) Step \(3 \mathrm{~N}_{2} \mathrm{O}_{4} \rightarrow \mathrm{NO}_{2}+\mathrm{NO}_{2}\) (fast)

For the reversible, one-step reaction \(\mathrm{A}+\mathrm{B} \rightleftarrows \mathrm{C}+\mathrm{D}\), the forward rate constant is \(52.4 \mathrm{~L} \cdot \mathrm{mol}^{-1} \cdot \mathrm{h}^{-1}\) and the rate constant for the reverse reaction is \(32.1 \mathrm{~L} \cdot \mathrm{mol}^{-1} \cdot \mathrm{h}^{-1}\). The activation energy was found to be \(35.2 \mathrm{~kJ} \cdot \mathrm{mol}^{-1}\) for the forward reaction and \(44.0 \mathrm{~kJ} \cdot \mathrm{mol}^{-1}\) for the reverse reaction. (a) What is the equilibrium constant for the reaction? (b) Is the reaction exothermic or endothermic? (c) What will be the effect of raising the temperature on the rate constants and the equilibrium constant?

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