Chapter 18: Problem 11
Give the systematic name of (a) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{3}\); (b) \(\mathrm{CH}_{3} \mathrm{CH}_{3}\); (c) \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{CH}_{3}\); (d) \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHCH}\left(\mathrm{CH}_{3}\right)_{2}\).
Short Answer
Expert verified
The IUPAC names are (a) propane, (b) ethane, (c) pentane, and (d) 2,2-dimethylpropane.
Step by step solution
01
Identify the Longest Carbon Chain
Count the number of carbon atoms in the longest continuous chain. The length of this chain determines the base name of the hydrocarbon.
02
Determine the Root Name
Based on the number of carbons in the longest chain, determine the root name using the IUPAC nomenclature: 1 carbon is 'meth-', 2 carbons 'eth-', 3 carbons 'prop-', and so on.
03
Identify and Name Substituents
Identify any substituents attached to the main chain and name them according to the number of carbon atoms they contain. Alkyl groups for 1, 2, and 3 carbon atoms are 'methyl-', 'ethyl-', and 'propyl-', respectively.
04
Assign Numbers to the Chain
Number the chain starting from the end nearest to the substituent in the molecule to assign the lowest possible numbers to the substituents.
05
Assemble the Compound Name - (a)
For \(\mathrm{CH}_{3} \mathrm{CH}_{2}\mathrm{CH}_{3}\), the longest chain has 3 carbons and no substituents. The compound name is 'propane'.
06
Assemble the Compound Name - (b)
For \(\mathrm{CH}_{3} \mathrm{CH}_{3}\), the longest chain has 2 carbons and no substituents. The compound name is 'ethane'.
07
Assemble the Compound Name - (c)
For \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{CH}_{3}\), the longest chain has 5 carbons and no substituents. The compound name is 'pentane'.
08
Assemble the Compound Name - (d)
For \(\left(\mathrm{CH}_{3}\right)_{2}\mathrm{CHCH}\left(\mathrm{CH}_{3}\right)_{2}\), the longest chain has 4 carbons. The substituents are two methyl groups at each end. The compound name is '2,2-dimethylpropane', ensuring number ordering.
Unlock Step-by-Step Solutions & Ace Your Exams!
-
Full Textbook Solutions
Get detailed explanations and key concepts
-
Unlimited Al creation
Al flashcards, explanations, exams and more...
-
Ads-free access
To over 500 millions flashcards
-
Money-back guarantee
We refund you if you fail your exam.
Over 30 million students worldwide already upgrade their learning with Vaia!
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Organic Chemistry
Organic chemistry is the study of the structure, properties, composition, reactions, and preparation of carbon-containing compounds, which include not only hydrocarbons but also compounds with any number of other elements, including hydrogen (most compounds contain at least one carbon-hydrogen bond), nitrogen, oxygen, halogens, phosphorus, silicon, and sulfur.
This branch of chemistry was originally limited to compounds produced by living organisms but has been broadened to include human-made substances such as plastics. The range of application of organic compounds is enormous and also includes, but is not limited to, pharmaceuticals, petrochemicals, food, explosives, paints, and cosmetics.
This branch of chemistry was originally limited to compounds produced by living organisms but has been broadened to include human-made substances such as plastics. The range of application of organic compounds is enormous and also includes, but is not limited to, pharmaceuticals, petrochemicals, food, explosives, paints, and cosmetics.
Chemical Nomenclature
Chemical nomenclature is a set of rules to generate systematic names for chemical compounds. The nomenclature used by chemists not only conveys the elements present in a compound but also the proportions and arrangement of these elements. The International Union of Pure and Applied Chemistry (IUPAC) establishes the rules for naming, ensuring that each compound has a unique clear name and that every name refers to a single structure.
IUPAC nomenclature is used for the naming of organic and inorganic compounds. For organic chemicals, it helps in identifying the molecule structure by giving details such as the length of the carbon chain, the functional groups attached, and the position of double or triple bonds if present.
IUPAC nomenclature is used for the naming of organic and inorganic compounds. For organic chemicals, it helps in identifying the molecule structure by giving details such as the length of the carbon chain, the functional groups attached, and the position of double or triple bonds if present.
Hydrocarbon Naming
Hydrocarbon naming follows a systematic method to ensure consistency and clarity in chemical communication. For naming hydrocarbons, IUPAC nomenclature takes into account the number of carbon atoms, the type of bonds between the atoms, and the presence of any functional groups.
Step-by-Step Hydrocarbon Naming Process
- Identify the parent chain: The longest continuous chain of carbon atoms gives the base of the compound's name.
- Determine the root name: The number of carbons in the chain dictates the root name. For example, one carbon is 'meth-', two is 'eth-', and so on.
- Identify substituents: Any branches or groups attached to the main chain are called substituents, and they are named according to their structure.
- Assign position numbers: The carbon atoms in the main chain are numbered from the end nearest a substituent to give the lowest possible numbers to the substituents.
- Assemble the name: The final name combines the substituents (with their position numbers) and the parent hydrocarbon name. Use prefixes like 'di-', 'tri-', 'tetra-', etc., if there are multiple identical substituents.