A flask of volume \(5.00 \mathrm{~L}\) is evacuated and \(43.78 \mathrm{~g}\) of
solid dinitrogen tetroxide, \(\mathrm{N}_{2} \mathrm{O}_{4}\), is introduced at
\(-196^{\circ} \mathrm{C}\). The sample is then warmed to \(25^{\circ}
\mathrm{C}\), during which time the \(\mathrm{N}_{2} \mathrm{O}_{4}\) vaporizes
and some of it dissociates to form brown \(\mathrm{NO}_{2}\) gas. The pressure
slowly increases until it stabilizes at \(2.96\) atm. (a) Write a balanced
equation for the reaction. (b) If the gas in the flask at \(25^{\circ}
\mathrm{C}\) were all \(\mathrm{N}_{2} \mathrm{O}_{4}\), what would the pressure
be? (c) If all the gas in the flask converted into \(\mathrm{NO}_{2}\), what
would the pressure be? (d) What are the mole fractions of \(\mathrm{N}_{2}
\mathrm{O}_{4}\) and \(\mathrm{NO}_{2}\) once the pressure stabilizes at \(2.96
\mathrm{~atm}\) ?