(a) Describe three ways in which you could increase the internal energy of an open system. (b) Which of these methods could you use to increase the internal energy of a closed system? (c) Which, if any, of these methods could you use to increase the internal energy of an isolated system?

Short Answer

Expert verified
To increase the internal energy of an open system, you can add heat, do work, or add mass with high internal energy. For a closed system, you can add heat or do work. There is no external method to increase the internal energy of an isolated system.

Step by step solution

01

Identifying Ways to Increase Internal Energy in an Open System

To increase the internal energy of an open system you can: 1) Add heat to the system (Q > 0), where energy is transferred as heat crosses the system's boundary. 2) Do work on the system (W > 0), implying external forces act on the system in a way that increases its energy. 3) Allow mass to enter the system with higher internal energy, as mass carries energy with it.
02

Applying Methods to a Closed System

In a closed system, where no mass can enter or leave, the internal energy can be increased by: 1) Adding heat to the system. 2) Doing work on the system. The transfer of mass is not applicable in a closed system.
03

Evaluating Methods for an Isolated System

An isolated system cannot exchange heat, work, or mass with its surroundings. Consequently, the internal energy of an isolated system cannot be increased by any external means. Any change must come from within the system, such as through internal reactions or changes in the states of its components.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Internal Energy
Internal energy refers to the total energy contained within a system, encompassing both the kinetic energy of particles moving and vibrating and the potential energy resulting from the forces between these particles. A core principle of thermodynamics is that internal energy can be altered through various interactions with its surroundings. For instance, heating a gas increases the speed of its particles, which in turn elevates the system's internal energy. To visualize this, imagine a pot of water on a stove; as the water heats up, the increased motion of the water molecules contributes to a rise in the water's internal energy. Similarly, compressing a gas within a piston does work on the system, thereby increasing its internal energy.
Open System
An open system is one that freely exchanges both energy and matter with its environment. A boiling kettle, for example, loses water to the surrounding air as steam and absorbs heat from the stove burner. Increasing the internal energy of an open system could involve adding heat, performing work on the system, or introducing mass with higher energy into the system. The concept plays a vital role in understanding various physical, biological, and chemical processes where exchange with the surroundings is essential for the system's function.
Closed System
Contrary to an open system, a closed system allows for the transfer of energy in the form of heat or work, but not mass. An example of this could be a sealed, inflated balloon — it can absorb heat from its environment or have work done on it when squeezed, but no air (mass) can enter or leave. This understanding is crucial when considering systems where maintaining a constant mass is necessary for accurate analysis or for specific operational requirements, such as in refrigeration systems or hydraulic pistons.
Isolated System
An isolated system is the 'fortress' of thermodynamic systems, where neither energy nor matter can pass through its boundaries. A perfect example, although theoretical, would be an insulated flask that perfectly retains heat and contains a vacuum around its contents, preventing any heat transfer or matter exchange. This concept is helpful when exploring theoretical predictions in thermodynamics since it provides a simplified environment free from external influences.
Heat Transfer
Heat transfer is the process by which thermal energy is exchanged between physical systems, depending on the temperature difference between them. The most familiar forms of heat transfer include conduction, convection, and radiation. In the context of increasing internal energy, when a system absorbs heat (think of a metal rod becoming hot at one end when heated at the other), the energy of the particles within the system increases. This concept is paramount in disciplines such as meteorology, engineering, and environmental science, where heat exchange is a fundamental phenomenon.
Work Done on System
The term 'work done on system' in thermodynamics often involves forces causing displacement within a system, which in turn increases the system's internal energy. An everyday example would be pumping air into a bicycle tire. The work done by the pump on the air inside the tire increases the air's internal energy and, subsequently, the tire's pressure. It's a crucial concept in understanding how energy transformations can be harnessed, controlled, and utilized in mechanical systems and engines.

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Most popular questions from this chapter

(a) Calculate the value of \(w\) for a system that releases \(216 \mathrm{~kJ}\) of heat in a process for which the decrease in internal energy is \(184 \mathrm{~kJ}\). (b) Is work done on or by the system during this process?

Barium metal is produced by the reaction of aluminum metal with barium oxide. From the standard reaction enthalpies $$ \begin{array}{ll} 2 \mathrm{Ba}(\mathrm{s})+\mathrm{O}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{BaO}(\mathrm{s}) & \Delta H^{\circ}=-1107 \mathrm{~kJ} \\ 2 \mathrm{Al}(\mathrm{s})+\frac{3}{2} \mathrm{O}_{2}(\mathrm{~g}) \longrightarrow \mathrm{Al}_{2} \mathrm{O}_{3}(\mathrm{~s}) & \Delta H^{\circ}=-1676 \mathrm{~kJ} \end{array} $$ calculate the reaction enthalpy for the production of metallic barium in the reaction: $$ 3 \mathrm{BaO}(\mathrm{s})+2 \mathrm{Al}(\mathrm{s}) \stackrel{\Delta}{\longrightarrow} \mathrm{Al}_{2} \mathrm{O}_{3}(\mathrm{~s})+3 \mathrm{Ba}(\mathrm{s}) $$

In a combustion cylinder, the total internal energy change produced from the burning of a fuel is \(-2.573 \mathrm{~kJ}\). The cooling system that surrounds the cylinder absorbs \(947 \mathrm{~kJ}\) as heat. How much work can be done by the fuel in the cylinder?

The enthalpy of formation of trinitrotoluene (TNT) is \(-67 \mathrm{~kJ} \cdot \mathrm{mol}^{-1}\), and the density of TNT is \(1.65 \mathrm{~g}^{-3} \mathrm{~cm}^{-3}\). In principle, it could be used as a rocket fuel, with the gases resulting from its decomposition streaming out of the rocket to give the required thrust. In practice, of course, it would be extremely dangerous as a fuel because it is sensitive to shock. Explore its potential as a rocket fuel by calculating its enthalpy density (enthalpy released per liter) for the reaction $$ \begin{aligned} 4 \mathrm{C}_{7} \mathrm{H}_{5} \mathrm{~N}_{3} \mathrm{O}_{6}(\mathrm{~s})+21 \mathrm{O}_{2}(\mathrm{~g}) & \longrightarrow \\ 28 \mathrm{CO}_{2}(\mathrm{~g})+10 \mathrm{H}_{2} \mathrm{O}(\mathrm{g})+6 \mathrm{~N}_{2}(\mathrm{~g}) \end{aligned} $$

Predict the contribution to the heat capacity \(C_{V, \mathrm{~m}}\) made by molecular motions for each of the following atoms and molecules: (a) \(\mathrm{HCN}\); (b) \(\mathrm{C}_{2} \mathrm{H}_{6}\); (c) Ar; (d) HBr.

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