Chapter 12: Problem 10
A 15.00-mL. sample of oxalic acid, \(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}\) (with two acidic protons), was titrated to the stoichiometric point with \(17.02 \mathrm{~mL}\) of \(0.288 \mathrm{M} \mathrm{NaOH}(a q)\). (a) What is the molarity of the oxalic acid? (b) Dctermine the mass of oxalic acid in the solution.
Short Answer
Step by step solution
- Write down the balanced chemical equation
- Calculate the moles of NaOH used
- Calculate the moles of oxalic acid
- Calculate the molarity of oxalic acid
- Determine the molar mass of oxalic acid
- Calculate the mass of oxalic acid
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemical Stoichiometry
In the provided exercise, stoichiometry is used to determine the relationship between the reactants: oxalic acid, which has two acidic protons, and sodium hydroxide. Here, the balanced chemical equation is of paramount importance as it reveals the mole ratio between reactants and products. We observe that two moles of sodium hydroxide neutralize one mole of oxalic acid, showcasing a 2:1 ratio.
To successfully interpret or predict the outcomes of chemical reactions, mastering stoichiometry is indispensable. It enables us to accurately quantify how much reactant is needed to produce a certain amount of product, which is crucial for this titration.
Molarity Calculation
The molarity of a solution is found by dividing the number of moles of the solute by the volume of the solution in liters. It's imperative to ensure that the volume is converted to liters if it’s given in milliliters or any other unit to ensure uniformity in the calculation. In educational contexts, elucidating the process of molarity calculation fosters a deeper understanding of solution concentration and assists in the prediction of reactions' outcomes in various scenarios.
Acid-Base Titration
The exercise requires performing a titration of oxalic acid with sodium hydroxide. By calculating the point at which the acidic protons of oxalic acid have completely reacted with the hydroxide ions from the sodium hydroxide, we can deduce the exact amount of acid in the original solution. Emphasizing the importance of precision and understanding the end-point readouts are vital in the learner’s competency in performing titrations.
Moles and Molar Mass
In our oxalic acid exercise, determining the moles of the substance involved in the reaction is a crucial step. It is followed by calculating the mass of the oxalic acid using its molar mass, incorporating the atomic masses of carbon, hydrogen, and oxygen. These concepts are intertwined; understanding the relationship between moles, molar mass, and mass is fundamental for solving problems in stoichiometry and for conducting various other calculations in chemistry.