In a titration, a \(3.25 \mathrm{~g}\) sample of an acid, HX, requires \(68.8 \mathrm{~mL}\) of a \(0.750 \mathrm{M} \mathrm{NaOH}(\mathrm{aq})\) solution for complete reaction. What is the molar mass of the acid?

Short Answer

Expert verified
The molar mass of the acid, HX, is \frac{3.25 g}{0.0516 moles} which equals approximately 62.98 g/mol.

Step by step solution

01

Calculate moles of NaOH

Use the molarity and volume of the NaOH solution to calculate the moles of NaOH that reacted with the acid. The formula for calculating moles is: moles = molarity × volume (in liters). So, moles of NaOH = 0.750 M × 68.8 mL × (1 L / 1000 mL).
02

Determine moles of acid, HX

Understand that in a titration, the moles of acid will be equal to the moles of base used if the reaction between them is 1:1. As no other information is given about the stoichiometry, assume a 1:1 molar ratio and set the moles of NaOH equal to the moles of HX.
03

Calculate molar mass of the acid, HX

Use the formula: molar mass = mass of substance (in grams) / moles of substance. Apply the previously found mass of the acid (3.25 g) and the calculated moles of the acid to find its molar mass.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Titration Analysis
Titration analysis is a laboratory method used to determine the concentration of a solution, such as an acid or a base. By accurately measuring the volume of a known concentration of titrant added to a sample until the reaction reaches completion (the equivalence point), the unknown concentration of the sample can be calculated.

During a titration, indicators or pH meters may be used to pinpoint the endpoint, which indicates the equivalence point has been reached. A common titration, like the one in the textbook exercise, involves a strong acid and a strong base reaction. Precise calculations and measurements are crucial for a successful titration analysis, as they directly impact the accuracy of the final result.
Stoichiometry
Stoichiometry is the study of the quantitative relationships, or ratios of amounts, between substances involved in chemical reactions. It is based on the law of conservation of mass, where the total mass of reactants equals the mass of products.

For the exercises involving titrations, stoichiometry allows us to determine the moles of acid based on the moles of base used in the reaction. If no other information is provided, it is often safe to assume a 1:1 ratio for a reaction between a strong acid and a strong base, except when dealing with polyprotic acids or other complex reactions. Stoichiometry can be challenging for many students, but it forms the core of chemical calculations in reactions.
Molarity of Solutions
The molarity of a solution is a way of expressing concentration, defined as the number of moles of solute per liter of solution.The units for molarity are moles per liter (M). Calculating molarity involves knowing the amount of substance in moles and the total volume of the solution. Being essential for titrations, the concept of molarity is used to determine how much of the titrant should be added to the analyte to reach the endpoint. In our exercise, the molarity of sodium hydroxide (NaOH) plays a key role in finding the molar mass of the unknown acid.
Acid-Base Reactions
Acid-base reactions are fundamental chemical reactions where an acid reacts with a base to produce water and a salt. This type of reaction is central to many titration problems. Understanding the nature of acids and bases, their strengths, and how they interact is vital.

As the strong acid HX reacts with the strong base NaOH, knowing the stoichiometry of the reaction allows us to deduce that the products will be water (H2O) and the salt NaX. The detailed comprehension of acid-base reactions is not only important for titration analysis but also has broader implications in various scientific and industrial applications, including environmental science, medicine, and materials science.

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Most popular questions from this chapter

\(\mathbf{L} .4\) The compound diborane, \(\mathrm{B}_{2} \mathrm{H}_{6}\), was at one time considered for use as a rocket fuel. Its combustion reaction is $$ \mathrm{B}_{2} \mathrm{H}_{6}(\mathrm{~g})+3 \mathrm{O}_{2}(\mathrm{l}) \rightarrow 2 \mathrm{HBO}_{2}(\mathrm{~g})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{l}) $$ The fact that \(\mathrm{HBO}_{2}\), a reactive compound, was produced rather than the relatively inert \(\mathrm{B}_{2} \mathrm{O}_{3}\) was a factor in the discontinuation of the investigation of diborane as a fuel. (a) What mass of liquid oxygen (LOX) would be needed to burn \(50.0 \mathrm{~g}\) of \(\mathrm{B}_{2} \mathrm{H}_{6}\) ? (b) Determine the mass of \(\mathrm{HBO}_{2}\) produced from the combustion of \(30.0 \mathrm{~g}\) of \(\mathrm{B}_{2} \mathrm{H}_{6}\).

A 15.00-mL. sample of oxalic acid, \(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}\) (with two acidic protons), was titrated to the stoichiometric point with \(17.02 \mathrm{~mL}\) of \(0.288 \mathrm{M} \mathrm{NaOH}(a q)\). (a) What is the molarity of the oxalic acid? (b) Dctermine the mass of oxalic acid in the solution.

A vitamin C tablet was analyzed to detcrmine whether it did in fact contain, as the manufacturer claimed, \(1.0 \mathrm{~g}\) of the vitamin. A tablet was dissolved in water to form a \(100.00-\mathrm{mL}\). solution, and a \(10.0-\mathrm{mL}\). sample was titrated with iodine (as potassium triiodide). It required \(10.1 \mathrm{~mL}\) of \(0.0521 \mathrm{MI}_{3}\) (aq) to reach the stoichiometric point in the titration, Given that \(1 \mathrm{~mol} \mathrm{I}_{3}^{-}-1 \mathrm{~mol}\) vitamin \(\mathrm{C}\) in the reaction, is the manufacturer's claim correct? The molar mass of vitamin \(\mathrm{C}\) is \(176 \mathrm{~g} \cdot \mathrm{mol}^{-1}\).

A 15.00-mL. sample of sodium hydroxide was titrated to the stoichiometric point with \(17.40 \mathrm{~mL}\). of \(0.234 \mathrm{M} \mathrm{HCl}(\mathrm{aq})\). (a) What is the initial molarity of \(\mathrm{NaOH}\) in the solution? (b) Calculate the mass of \(\mathrm{NaOH}\) in the solution.

In a titration, \(16.02 \mathrm{~mL}\) of \(0.100 \mathrm{M} \mathrm{NaOH}(\mathrm{aq})\) was required to titrate \(0.2011 \mathrm{~g}\) of an unknown acid, \(\mathrm{HX}\). What is the molar mass of the acid?

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