Chapter 2: Problem 25
On the basis of the expected charges on the monatomic ions, give the chemical formula of each of the following compounds: (a) magnesium arsenide; (b) indium sulfide; (c) aluminum hydride; (d) hydrogen telluride; (c) bismuth(III) fluoride.
Short Answer
Expert verified
The chemical formulas for the given compounds are (a) Mg3As2, (b) In2S3, (c) AlH3, (d) H2Te, (e) BiF3.
Step by step solution
01
Identify Charge of Magnesium Ion
Magnesium generally forms a +2 charge as it is in group 2 of the periodic table and tends to lose two electrons to attain a stable electron configuration similar to the noble gases.
02
Identify Charge of Arsenide Ion
Arsenide refers to the anion formed by arsenic. Arsenic commonly forms a -3 charge, as it is in group 15 of the periodic table and tends to gain three electrons to attain a stable configuration.
03
Write the Formula for Magnesium Arsenide
To write the formula for magnesium arsenide, combine Mg and As ions in a ratio that neutralizes their charges. The formula is Mg3As2, resulting in an overall neutral charge.
04
Identify Charge of Indium Ion
Indium generally forms a +3 charge as it is in group 13 of the periodic table and has three valence electrons it can lose.
05
Identify Charge of Sulfide Ion
Sulfide refers to the anion formed by sulfur. Sulfur commonly forms a -2 charge as it is in group 16 and tends to gain two electrons to reach a stable electron configuration.
06
Write the Formula for Indium Sulfide
To write the formula for indium sulfide, combine In and S ions in a ratio that neutralizes their charges. The formula is In2S3.
07
Identify Charge of Aluminum Ion
Aluminum tends to form a +3 charge as it is in group 13 and can lose three electrons to achieve a stable electron configuration.
08
Identify Charge of Hydride Ion
Hydride refers to the anion of hydrogen, which commonly forms a -1 charge as it gains one electron to attain a full shell, like helium.
09
Write the Formula for Aluminum Hydride
To write the formula for aluminum hydride, combine Al and H ions in a ratio that neutralizes their charges. The formula is AlH3.
10
Identify Charge of Hydrogen Ion in Hydrogen Telluride
In hydrogen telluride, hydrogen acts as a cation with a +1 charge since it can lose one electron.
11
Identify Charge of Telluride Ion
Telluride refers to the anion formed by tellurium, which commonly forms a -2 charge as it gains two electrons to reach a stable configuration.
12
Write the Formula for Hydrogen Telluride
The formula for hydrogen telluride includes two hydrogen ions for every tellurium ion to balance the charges, resulting in H2Te.
13
Identify Charge of Bismuth Ion in Bismuth(III) Fluoride
Bismuth(III) indicates that bismuth forms a +3 charge.
14
Identify Charge of Fluoride Ion
Fluoride ion has a -1 charge because it gains one electron to complete its outer electron shell.
15
Write the Formula for Bismuth(III) Fluoride
To neutralize the charges, three fluoride ions are needed for each bismuth ion, giving the formula BiF3.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemical Formula Writing
Writing chemical formulas is a fundamental skill in chemistry that allows us to represent compounds clearly and concisely. For example, when writing the formula for magnesium arsenide, we start by understanding that magnesium (Mg) has a +2 charge. Following this, we consider arsenide (As) with a -3 charge. The aim is to combine these ions in a ratio that balances the overall charge of the compound. A simple cross-multiplication method is applied: the charge of magnesium becomes the subscript of arsenide, and vice versa, giving us \( Mg_3As_2 \). The subscript indicates the number of ions needed to balance the charge, ensuring the resulting compound is neutral. This method is universally applicable, whether it's for indium sulfide \( In_2S_3 \), aluminum hydride \( AlH_3 \), or bismuth(III) fluoride \( BiF_3 \). Recognizing the charge of each ion based on its position in the periodic table is key to writing the correct formula.
Monatomic Ions Charge
Monatomic ions are atoms that have lost or gained electrons, which creates a charge. This charge is determined by the atom's group number in the periodic table. For instance, magnesium, which is in group 2, loses two electrons to attain stability, resulting in a +2 charge. Conversely, arsenic, in group 15, gains three electrons, acquiring a -3 charge to achieve a stable electron configuration. When forming compounds, monatomic ions combine in such a way that their total charge is neutralized. This can be determined through the octet rule, where atoms aim to have an outer shell resembling a noble gas, either by shedding electrons to form positive cations or by gaining electrons to form negative anions. Understanding the charges of ions is a crucial step in predicting the ratios in which they combine, which is necessary to write correct chemical formulas.
Periodic Table Groups
The periodic table is arranged in columns known as groups that share chemical and physical properties. Elements in the same group typically have similar valence electron configurations, which directly influences their ability to form ions. Group 1 elements lose one electron to form +1 charged ions, while group 16 elements gain two electrons to form -2 charged ions. This predictable behavior facilitates the formation of ionic compounds, such as hydrogen telluride \( H_2Te \), where the group 1 element hydrogen forms a +1 cation and the group 16 element tellurium forms a -2 anion. Group numbers can provide a quick reference for determining the common charges of monatomic ions, though there are exceptions to these patterns. Nevertheless, acknowledging these groups is instrumental in anticipating how different elements will react and in what proportion they will form compounds.