Which of the following members of cach pair is the stronger Lewis base? Explain your reasoning. (a) \(\mathrm{CH}_{3}^{-}\)or \(\mathrm{CH}_{4}\); (b) \(\mathrm{H}_{2} \mathrm{O}\) or \(\mathrm{H}_{2} \mathrm{~S}\); (c) \(\mathrm{NH}_{3}\) or \(\mathrm{NH}_{2}^{-}\).

When it comes to understanding the nature of chemical interactions, the term 'Lewis base' becomes a fundamental concept. A Lewis base is a substance that readily offers a pair of electrons to form a covalent bond. This generosity of sharing electrons qualifies it as a pivotal player in chemical bonding, especially when it interacts with a Lewis acid, which accepts the electrons.

Imagine a Lewis base as a kind-hearted individual in a partnership who is always ready to give and support. In the dance of chemical reactions, the Lewis base is the one extending its hands (electron pairs) to the Lewis acid for a captivating duet, forming a bond that is both stable and significant.

The whole idea of a Lewis base revolves around its ability to donate an electron pair. This act of donation is like offering a gift that can create new bonds or strengthen existing ones in the molecular world. When evaluating the strength of a Lewis base, think of its electron pair as a magnet. If the magnet is strong, the base is a charismatic donor, attracting other atoms (Lewis acids) to accept its electron pair.

Who is the Generous Giver?

A molecule or ion with a negative charge typically has an abundance of electrons and, therefore, can donate with less hesitation. Compare this to a neutral molecule that might be a bit bashful, holding back its electrons. Thus, negatively charged species are usually stronger Lewis bases because they have more 'gifts' (electrons) to give away.

Electronegativity is a crucial concept when discussing Lewis bases. It measures how much an atom tugs on the electron blanket in a bond. In the realm of Lewis bases, lower electronegativity translates to a more generous electron donor. Why? It’s because atoms with lower electronegativity do not cling tightly to their electrons; they’re more willing to share.

Consider an analogy where electronegativity is like possessiveness in a relationship. Atoms with high electronegativity are the clingy partners, holding on to their electron pairs. Those with lower electronegativity are the free-spirited partners, ready to share their electron pairs and form stable bonds with their Lewis acid counterparts.