Naming ionic compounds requires an understanding of the elements that form them, specifically their ionic forms. Unlike covalent compounds, ionic compounds are formed by the electrostatic attraction between ions of opposite charges. Cations, which are usually metal ions, retain the name of the element, while anions, typically non-metals or polyatomic ions, have a name ending in '-ide,' '-ate,' or '-ite,' depending on the ion.
Rules and Examples
- For monoatomic anions like \( \mathrm{Cl}^- \), the name ends with '-ide,' making it chloride in \( \mathrm{Hg_2Cl_2} \) which becomes Mercury(I) chloride.
- For polyatomic anions like \( \mathrm{HCO_3}^- \) (bicarbonate), the name remains as is in the pairing with sodium (Na), hence Sodium Bicarbonate for \( \mathrm{NaHCO_3} \).
- For ionic compounds with transition metals, a Roman numeral denotes the metal ion's charge, as seen with zinc in \( \mathrm{ZnO} \) as Zinc Oxide, no charge is indicated since zinc has a consistent charge.
These conventions allow chemists to communicate chemical compounds' compositions effectively.