If the edge length of a foc unit cell of \(\mathrm{Rbl}\) is \(732.6 \mathrm{pm}\), how large must the edge length of a cubic single crystal of Rbl be in order for it to contain \(1.00 \mathrm{~mol}\) RbI?

Short Answer

Expert verified
The edge length of the cubic single crystal of RbI containing one mole is the cube root of \( (\frac{6.022 \times 10^{23}}{4}) \times (732.6 \times 10^{-12} \mathrm{m})^3 \).

Step by step solution

01

Determine the Number of Formula Units in One Mole

The number of formula units in one mole is given by Avogadro's number, which is approximately 6.022 x 10^23 formula units per mole.
02

Determine the Number of Formula Units per FCC Unit Cell

In a face-centered cubic (FCC) unit cell, there are 4 formula units per unit cell.
03

Calculate the Number of Unit Cells in One Mole

Divide Avogadro’s number by the number of formula units per FCC unit cell to get the number of unit cells in one mole: \( \frac{6.022 \times 10^{23}}{4} \).
04

Calculate the Volume of One Mole of Unit Cells

Using the edge length of a single FCC unit cell, the volume of one unit cell can be calculated as \( V_{\mathrm{cell}} = a^3 \), where \( a \) is the edge length of the unit cell. The volume of one mole of unit cells is then the volume of one unit cell multiplied by the number of unit cells in one mole.
05

Find the Cube Root of the Volume of One Mole

To find the edge length of the large cube that would contain one mole of RbI, take the cube root of the volume of one mole of unit cells.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Avogadro's Number
When studying chemistry, Avogadro's number is a fundamental constant that you're likely to encounter frequently. It represents the number of atoms, ions, or molecules in one mole of a substance, which is approximately 6.022 x 10^23. This staggering number defines the bridge between the microscopic particles we cannot see and the measurable quantities we handle in a laboratory.

For example, if you have one mole of water, you essentially have 6.022 x 10^23 water molecules. Understanding Avogadro's number is crucial when dealing with conversions between the number of particles and the amount in moles for any given substance. It allows scientists to calculate the number of atoms or molecules required to react to form a certain amount of product in chemical reactions.
Formula Units per Mole
In the world of crystalline solids, the term 'formula units' refers to the simplest ratio of the ions that represent the compound's composition. A formula unit is essentially the building block of a crystal structure. When you're considering a mole of a substance, you're thinking about 6.022 x 10^23 of these basic units.

For salts and ionic compounds like RbI (rubidium iodide), the concept of formula units per mole becomes very significant. In the given problem, the idea was to understand how many basic units are packed inside the crystal lattice. This helps calculate the amount of substance needed for chemical reactions or to determine the structure and volume of the crystal containing a mole of ions. With ionic compounds, this information can be vital for predictions about the compound's physical properties or reactivity.
Crystal Lattice
A crystal lattice is the symmetrical three-dimensional arrangement of atoms inside a crystal. Every solid has its own unique arrangement that defines its structural integrity and properties. The face-centered cubic (FCC) unit cell, mentioned in the problem, is one of the most common lattice types–think of salt or diamonds.

Within such a lattice, atoms, ions, or molecules are positioned at each corner and at the center of each face of the cube, creating a distinctive pattern that repeats in all directions. This geometric layout within crystalline solids is not just theoretically interesting but practically important too, as it influences melting points, solubility, and other chemical characteristics of the material. When a substance like RbI forms a crystal lattice, the arrangement largely dictates its physical properties and how it interacts with other substances.
Molar Volume
The molar volume of a substance is the volume occupied by one mole of it at a given temperature and pressure. For a crystalline substance such as RbI, the molar volume can be thought of as a large cube made up of FCC unit cells. You would calculate it by determining the volume of one unit cell and multiplying it by the number of cells present in one mole.

In this context, molar volume provides insight into the density and the space requirements of the substance. Knowing the molar volume of a substance also allows chemists to understand how much space the substance will take up which is critical for things such as designing storage for materials or planning chemical syntheses where volumes of reactants matter. The exercise provided uses the concept of molar volume to determine how large a single crystal should be to contain a whole mole of RbI, a computation that is fundamental to practical applications in material science and chemistry.

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Most popular questions from this chapter

Tetrahedral and octahedral interstitial holes are formed by the spaces left when anions pack in a cubic close-packed array. (a) Which hole can accommodate the larger ions? (b) What is the size ratio of the largest metal cation that can occupy an octahedral hole to the largest that can occupy the tetrahedral hole while maintaining the close-packed nature of the anion lattice? (c) If half the tetrahedral holes are occupied, what will the chemical formula of the compound \(\mathrm{M}_{2} \mathrm{~A}_{2}\) be, where \(\mathrm{M}\) represents the cations and \(\mathrm{A}\) the anions?

Place the following types of molecular and ion interactions in order of increasing magnitude: (a) iondipole; (b) induced dipole-induced dipole; (c) dipoledipole in the gas phase; (d) ion-ion; (e) dipole-dipole in the solid phase.

The metal polonium (which was named by Maric Curie after her homeland, Poland) crystallizes in a primitive cubic strucrure, with an atom at each corner of a cubic unit cell. The atomic radius of polonium is \(167 \mathrm{pm}\). Sketch the unit cell and determine (a) the number of atoms per unit cell; (b) the coordination number of an atom of polonium; (c) the length of the side of the unit cell.

For which of the following molecules will dipoledipole interactions be important: (a) \(\mathrm{CH}_{4} ;\) (b) \(\mathrm{CH}_{3} \mathrm{Cl}\); (c) \(\mathrm{CH}_{2} \mathrm{Cl}_{2}\); (d) \(\mathrm{CHCl}_{3}\); (e) \(\mathrm{CCl}_{4}\) ?

Account for the following observations in terms of the type and strength of intermolecular forces. (a) The melting point of xenon is \(-112^{\circ} \mathrm{C}\) and that of argon is \(-189^{\circ} \mathrm{C}\). (b) The vapor pressure of diethyl ether \(\left(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OC}_{2} \mathrm{H}_{3}\right)\) is greater than that of water. (c) The boiling point of pentane, \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{CH}_{3}\), is \(36.1^{\circ} \mathrm{C}\), whereas that of 2,2 -dimethylpropane (also known as neopentane) is \(9.5^{\circ} \mathrm{C}\).

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