Identify the following systems as open, closed, or isolated: (a) gasoline burning in an automobile enginc; (b) mercury in a thermometer; (c) a living plant.

Short Answer

Expert verified
The gasoline burning in an automobile engine is an open system, the mercury in a thermometer is a closed system, and a living plant is an open system.

Step by step solution

01

Analyze Gasoline Burning in an Automobile Engine

To determine whether the system is open, closed, or isolated, consider whether the system exchanges energy and matter with its surrounding. Burning gasoline in an engine involves both energy transfer (heat and work) and mass transfer (gasoline and exhaust gases); hence, it is an open system.
02

Evaluate Mercury in a Thermometer

Mercury in a thermometer does not exchange matter with its surroundings since it is encapsulated, but it does exchange energy in the form of heat; thus, it is a closed system.
03

Assess a Living Plant

A living plant exchanges both matter (CO2, O2, water, nutrients) and energy (light for photosynthesis, heat) with its environment, making it an open system.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Open System
In thermodynamics, an open system is a system that freely exchanges both energy and matter with its surroundings. An example from the exercise is a living plant and an automobile engine burning gasoline. In the case of the plant, it absorbs carbon dioxide, water, and nutrients, and captures light energy for photosynthesis while also releasing oxygen and heat. Similarly, an automobile engine takes in gasoline and oxygen, produces energy to power the vehicle, and emits exhaust gases. Understanding open systems, especially their dynamic nature of interaction with the environment, is fundamental in fields ranging from engineering to biology.

Closed System
A closed system, unlike an open system, does not exchange matter with its surroundings but can exchange energy. A practical example provided in the exercise is mercury in a thermometer. The mercury can change its volume (thus doing work) and temperature in response to the surrounding temperature. This is crucial because closed systems allow us to study the effects of energy changes (like heat transfer) without the complications of changing composition due to matter exchange.

Isolated System
An isolated system is quite theoretical, as it neither exchanges matter nor energy with its surroundings. In reality, a perfect isolated system does not exist, but a thermos bottle is a close approximation as it minimizes heat and mass transfer with the environment. Understanding isolated systems provides a simplified model to analyze complex systems and processes without external influences, commonly used in thought experiments within physics.

Energy Exchange
The concept of energy exchange is central to understanding thermodynamic systems. Energy can be transferred in different forms, including heat and work. In the exercise, energy exchange is demonstrated through the heat absorbed and emitted by mercury in a thermometer and the energy conversions occurring in an automobile engine. In thermodynamics, the study of energy exchange helps us quantify how systems react to changes in their surroundings and is a foundation for engine design, climate control, and more.

Matter Exchange
Whereas energy exchange looks at how energy moves between a system and its surroundings, matter exchange refers to the physical exchange of components. For instance, in the open system of a living plant, there is a continuous exchange of gases and nutrients that sustain its growth and metabolic processes. Understanding matter exchange is essential in fields such as environmental science, chemical engineering, and indeed, all of life sciences.

Thermodynamics
The field of thermodynamics deals with the principles governing the relationships between heat, work, temperature, and energy. The examples provided in the exercise—a burning car engine, mercury in a thermometer, and a living plant—are all cases that exhibit different facets of thermodynamic laws and concepts like energy conservation and entropy. Grasping these concepts is vital for disciplines reaching from mechanical engineering to environmental science, as thermodynamics helps predict system behavior under various conditions.

Chemical Principles
Essential chemical principles are at play in all thermodynamic systems, particularly in open and closed systems that involve chemical reactions. For example, the combustion of gasoline in an engine is a chemical process that releases energy and results in new chemical products like CO2 and water. Chemical principles are intertwined with thermodynamics because they explain how energy is stored and released during molecular interactions and transformations - crucial for understanding the very foundation of matter and energy interactions.

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Most popular questions from this chapter

(a) Near room temperature the specific heat capacity of ethanol is \(2.42 \mathrm{~J} \cdot\left({ }^{\circ} \mathrm{C}\right)^{-1} \cdot \mathrm{g}^{-1}\). Calculate the heat that must be removed to reduce the temperature of \(150.0 \mathrm{~g}\) of \(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{OH}\) from \(50.0^{\circ} \mathrm{C}\) to \(16.6^{\circ} \mathrm{C}\). (b) What mass of copper can be heated from \(15^{\circ} \mathrm{C}\) to \(205^{\circ} \mathrm{C}\) when \(425 \mathrm{~kJ}\) of energy is available?

A gas sample in a piston axsembly expands, doing \(235 \mathrm{~kJ}\) of work on its surroundings at the same time that \(695 \mathrm{~kJ}\) of heat is added to the gas. (a) What is the change in internal encrgy of the gas churing this process? (b) Will the pressure of the gas be higher or lower when these changes are completed?

Strong sunshine bombards the Earth with about \(1 \mathrm{~kJ} \cdot \mathrm{m}^{-2}\) in \(1 \mathrm{~s}\). Calculate the maximum mass of pure ethanol that can be vaporized in 10 min from a beaker left in strong sunshine, assuming the surface area of the ethanol to be \(50 \mathrm{~cm}^{2}\). Assume all the heat is used for vaporization, not to increase the temperature.

A piece of metal of mass \(20.0 \mathrm{~g}\) at \(100.0^{\circ} \mathrm{C}\) is placed in a calorimeter containing \(50.7 \mathrm{~g}\) of watcr at \(22.0^{\circ} \mathrm{C}\). The final temperature of the mixture is \(25.7^{\circ} \mathrm{C}\) What is the specific heat capacity of the mctal? Assume that all the energy lost by the metal is gained by the water.

Identify the following systems as open, closed, or isolated: (a) coffec in a very high quality thermos bottle; (b) coolant in a refrigerator coil; (c) a bomb calorimeter in which benzene is bumed.

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