A chemist prepared an aqueous solution by mixing \(2.50 \mathrm{~g}\) of ammonium phosphate trihydrate, \(\left(\mathrm{NH}_{4}\right)_{3} \mathrm{PO}_{4} \cdot 3 \mathrm{H}_{2} \mathrm{O}\) and \(1.50 \mathrm{~g}\) of potassium phosphate, \(\mathrm{K}_{3} \mathrm{PO}_{4}\), with \(500 \mathrm{~g}\) of water. (a) Determine the number of moles of formula units of each compound that was measured. (b) How many moles of \(\mathrm{PO}_{4}{ }^{3-}\) are present in solution? (c) Calculate the mass of phosphate ions present in the solution. (d) What is the total mass of the water present in the solution?

Short Answer

Expert verified
The moles of ammonium phosphate trihydrate and potassium phosphate are calculated using their respective molar masses, then the moles of \(PO_4^{3-}\) are determined from both compounds. The mass of \(PO_4^{3-}\) ions is found by multiplying the moles of \(PO_4^{3-}\) by its molar mass. The total mass of the water includes the mass of the initial water plus the water from the ammonium phosphate trihydrate.

Step by step solution

01

Calculate Moles of Ammonium Phosphate Trihydrate

To find the number of moles of ammonium phosphate trihydrate \( (NH_4)_3PO_4 \cdot 3H_2O \), use the formula: \( n = \frac{m}{M} \), where \(m = 2.50 \text{g}\) is the mass of the compound and \(M\) is molar mass of the compound. Calculate \(M\) by using the periodic table to find the molar mass of each element and sum them up accordingly, considering their stoichiometry in the chemical formula.
02

Calculate Moles of Potassium Phosphate

Similarly, calculate the number of moles of potassium phosphate \(K_3PO_4\) using the formula \( n = \frac{m}{M} \), where \(m = 1.50 \text{g}\) is the mass of the compound and \(M\) is the molar mass. Find the molar mass of \(K_3PO_4\) in the same way as in Step 1.
03

Calculate Moles of Phosphate Ions

To find the total moles of \(PO_4^{3-}\) ions, sum up the moles of phosphate from both compounds. Each mole of ammonium phosphate trihydrate contributes 1 mole of \(PO_4^{3-}\) ions, and each mole of potassium phosphate also contributes 1 mole of \(PO_4^{3-}\) ions.
04

Calculate Mass of Phosphate Ions

To calculate the mass of phosphate ions in solution, multiply the total moles of \(PO_4^{3-}\) ions found in Step 3 by the molar mass of the phosphate ion.
05

Determine Total Mass of the Water in Solution

The total mass of the solution includes the mass of water plus the mass of both solutes. To find the total mass of water, add the given mass of water (500 g) to the mass of the water of crystallization present in ammonium phosphate trihydrate. There are 3 moles of \(H_2O\) per mole of this compound, calculate the mass contribution from these water molecules and add it to the initial water mass.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Stoichiometry
Stoichiometry is a branch of chemistry that deals with the quantitative relationships of the substances in chemical reactions. It allows chemists to predict the amounts of substances consumed and produced in a given reaction.

To understand stoichiometry, you must first grasp the concept of the mole, which is a standard scientific unit for measuring large quantities of very small entities such as atoms, molecules, or other specified particles. One mole is equivalent to Avogadro's number, which is approximately 6.022×1023 particles.

In the given exercise, stoichiometry is used to determine the number of moles of each compound by dividing the mass of the compound by its molar mass. This calculation is crucial for finding how much of each reactant is needed or how much of a product can be formed. Chemists also use stoichiometry to calculate the mass of substances produced in a chemical reaction, given the mass of the reactants.
Molar Mass Calculation
Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is calculated by summing the atomic masses of all atoms in a molecule as listed on the periodic table, taking into account their stoichiometric coefficients in the compound's chemical formula.

For instance, to find the molar mass of ammonium phosphate trihydrate \( (NH_4)_3PO_4 \cdot 3H_2O \), sum the atomic masses of nitrogen (N), hydrogen (H), phosphorus (P), and oxygen (O), remembering to count the atoms in the water of crystallization. Once the total molar mass is obtained, it can be used to convert between grams and moles, a critical step in many stoichiometric calculations.
Solution Concentration
Solution concentration describes how much solute is present in a given quantity of solvent and is commonly measured in terms of molarity (M), expressed as moles of solute per liter of solution.

In the exercise, the solution concentration is not directly calculated, but understanding the concept is important for further calculations and dilutions. The number of moles of solute present in the solution can be used to find molarity if the total volume of the solution is known. Concentration can also influence the reactivity and properties of a solution, underscoring its importance in chemical reactions and analysis.
Chemical Formula
A chemical formula provides important information about the composition of a compound. It indicates the types and numbers of atoms in a molecule, giving insight into the compound's proportions and stoichiometry. For a molecule like \( (NH_4)_3PO_4 \cdot 3H_2O \), the chemical formula shows that each unit contains three ammonium ions \( (NH_4)^+ \) and one phosphate ion \( (PO_4)^{3-} \) along with three water molecules (\text{3H}_2\text{O}\text{.)}

The chemical formula is pivotal in calculations of molar mass and in understanding the contributions of each ion to the properties of the compound, such as the number of phosphate ions contributing to the final concentration in a solution, as seen in the provided exercise.

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Most popular questions from this chapter

A student investigating the propertics of solutions containing carbonate ions prepared a solution containing \(7.112 \mathrm{~g}\) of \(\mathrm{Na}_{2} \mathrm{CO}_{3}\) in a \(250.0-\mathrm{mL}\) volumetric flask. Some of the solution was transferred to a burer. What volume of solution should be dispensed from the buret to provide (a) \(5.112 \times 10^{-3} \mathrm{~mol} \mathrm{Na}_{2} \mathrm{CO}_{3}\); (b) \(3.451 \times 10^{-3} \mathrm{~mol} \mathrm{CO}_{3}^{2-}\) ?

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Calculate the mole fraction of each component in the following solutions: (a) \(2.5 .0 \mathrm{~g}\) of water and \(50.0 \mathrm{~g}\) of ethanol, \(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{OH}\); (b) \(25.0 \mathrm{~g}\) of water and \(50.0 \mathrm{~g}\) of methanol, \(\mathrm{CH}_{3} \mathrm{OH}\); (c) a glucowe solution that is \(0.10 \mathrm{~m}\) \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(a q)\).

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The sulfuric acid solution that is purchased for a stockroom has a molarity of \(17.8\) M; all sulfuric acid solutions for experiments are prepared by dilution of this stock solution. (a) Determine the volume of \(17.8 \mathrm{M}\) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) that must be diluted to \(250 \mathrm{~mL}\) to prepare a \(2.0 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{aq})\) solution. (b) An experiment requires a \(0.50 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{aq})\) solution. The stockroom manager estimates that \(6.0\) L of the acid is needed. What volume of \(17.8 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{aq})\) must be used for the preparation?

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