In a laboratory exercise, a student mixes \(2.5 .0 \mathrm{~g}\) of cthanol, \(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{OH}\), with \(150 \mathrm{~g}\) of water. (a) What is the mole fraction of ethanol in the solution? (b) What is the molality of cthanol in the solution?

Short Answer

Expert verified
The mole fraction of ethanol is calculated using the number of moles of ethanol and water, and the molality is calculated using the moles of ethanol per kilogram of water.

Step by step solution

01

Calculate moles of ethanol

Determine the number of moles of ethanol using its molar mass. The molar mass of ethanol, \( \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH} \), is approximately 46.07 g/mol. Use the formula \( n = \frac{m}{M} \) where \( n \) is the number of moles, \( m \) is the mass of the substance, and \( M \) is the molar mass. Thus, \( n_{\text{ethanol}} = \frac{2.50 \text{ g}}{46.07 \text{ g/mol}} \).
02

Calculate moles of water

Calculate the number of moles of water using its molar mass. The molar mass of water is approximately 18.015 g/mol. Use the formula \( n = \frac{m}{M} \) to find \( n_{\text{water}} = \frac{150 \text{ g}}{18.015 \text{ g/mol}} \).
03

Calculate mole fraction of ethanol

The mole fraction \( X \) of a component is given by \( X = \frac{n_{\text{component}}}{n_{\text{total}}} \). Calculate the total moles \( n_{\text{total}} \) by adding moles of ethanol and water. Then use the formula to find the mole fraction of ethanol: \( X_{\text{ethanol}} = \frac{n_{\text{ethanol}}}{n_{\text{ethanol}} + n_{\text{water}}} \).
04

Calculate molality of ethanol

Molality \( b \) is defined as moles of solute per kilogram of solvent. Use the formula \( b = \frac{n_{\text{solute}}}{m_{\text{solvent}}} \) where \( n_{\text{solute}} \) is the moles of ethanol and \( m_{\text{solvent}} \) is the mass of water in kilograms. Calculate the molality: \( b_{\text{ethanol}} = \frac{n_{\text{ethanol}}}{0.150 \text{ kg}} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Mole Fraction Calculation
Understanding the mole fraction of a component within a solution is essential for many chemical calculations. The mole fraction, denoted as 'X', represents the proportion of a constituent to the total number of moles in the mixture. To calculate it, you simply divide the moles of the component by the total moles in the solution.

For instance, in our given exercise, the mole fraction of ethanol in the solution can be calculated by taking the number of moles of ethanol and dividing it by the sum of moles of ethanol and water combined. The formula is as follows:
\[\begin{equation}X_{\text{ethanol}} = \frac{n_{\text{ethanol}}}{n_{\text{ethanol}} + n_{\text{water}}}\end{equation}\]
Calculating the mole fraction is a straightforward process, however, ensuring accuracy in the number of moles for each component is crucial. Properly balancing the chemical equation, if applicable, is also an important preliminary step.
Molality Calculation
Molality, often represented by the symbol 'b', is a measure of the concentration of a solution that refers to the moles of solute per kilogram of solvent. Unlike molarity, molality is not affected by temperature changes because it's based on mass rather than volume. To calculate molality, we use the equation:
\[\begin{equation}b = \frac{n_{\text{solute}}}{m_{\text{solvent}}}\end{equation}\]
where 'n' is the moles of the solute, and 'm' is the mass of the solvent in kilograms. In the laboratory exercise, the mass of ethanol is first converted to moles, and then divided by the mass of water used as the solvent, with careful conversion to kilograms. By doing this, we can find the molality of ethanol in the solution. This step is crucial for many applications such as boiling point elevation and freezing point depression where solution concentration plays a significant role.
Molar Mass
Molar mass, the mass of one mole of a substance, is expressed in grams per mole (g/mol). It is a fundamental concept for converting between mass and moles of a substance. Each element's molar mass can be found on the periodic table, and the molar mass of a compound is the sum of the molar masses of its constituent atoms.

In this exercise, the molar mass of ethanol, C2H5OH, is calculated by summing the molar masses of two carbon atoms, six hydrogen atoms, and one oxygen atom. The accurate determination of molar mass is critical for subsequent calculations, such as mole fraction and molality. Understanding how to calculate molar mass allows students to transition smoothly from the mass of a substance to moles, a fundamental skill in chemistry.
Solution Concentration
Solution concentration is a measure of the amount of solute in a given amount of solution or solvent and is key in controlling the properties of a solution. There are several ways to express concentration, including molarity, molality, normality, and mole fraction. Each term provides valuable information depending on the nature of the problem being solved.

Molarity is moles of solute per liter of solution, while molality is moles of solute per kilogram of solvent, as explained earlier. Normality refers to equivalents of a solute per liter of solution and is often used in acid-base chemistry. Mole fraction is the ratio of the number of moles of a component to the total number of moles in the mixture. Understanding these different concepts is essential for correctly interpreting reaction conditions, predicting the outcomes of reactions, and in various industrial applications where precise concentrations are necessary.

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Most popular questions from this chapter

To prepare a very dilute solution, it is advisable to perform successive dilutions of a single prepared reagent solution, rather than to wcigh a very small mass or to measure a very small volume of stock chemical. A solution was prepared by transferring \(0.661 \mathrm{~g}\) of \(\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\) to a \(250.0\)-mL volumetric flask and adding water to the mark. A \(1.000-\mathrm{mL}\). sample of this solution. was transferred to a 500 -mL. volumetric flask and diluted to the mark with water. Then \(10.0 \mathrm{~mL}\) of the diluted solution was transferred to a 250 -mL. flask and diluted to the mark with water. (a) What is the final concentration of \(\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{\text {, in solution? (b) What }}\) mass of \(\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\) is in this final solution? (The answer to the last question gives the amount that would have had to have been weighed out if the solution had been prepared directly.)

Explain how you would prepare an aqueous solution of \(0.010 \mathrm{M} \mathrm{KMnO}_{4}(\mathrm{aq})\) starting with (a) solid \(\mathrm{KMnO}_{4} ;\) (b) \(0.050 \mathrm{M} \mathrm{KMnO}_{4}\) (aq).

What mass (in grams) of anhydrous sohute is needed to prepare each of the following solutions? (a) \(1.0 \mathrm{~L}\) of \(0.10 \mathrm{M} \mathrm{NaCl}(\mathrm{aq}) ;\) (b) \(250 \mathrm{~mL}\) of \(0.10 \mathrm{M}\) \(\mathrm{CaCl}_{2}(\mathrm{aq}) ;\) (c) \(500 \mathrm{~mL}\) of \(0.63 \mathrm{M} \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(\mathrm{aq})\).

(a) Determine the mass of anhydrous copper(II) sulfate that must be used to prepare \(250 \mathrm{~mL}\) of a \(0.20 \mathrm{M} \mathrm{CuSO}_{4}(\mathrm{aq})\) solution. (b) Determine the mass of \(\mathrm{CuSO}_{4}-5 \mathrm{H}_{2} \mathrm{O}\) that must be used to prepare \(250 \mathrm{ml}\). of a \(0.20 \mathrm{M} \mathrm{CuSO}_{4}(\mathrm{aq})\) solution.

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