What is meant by dynamic equilibrium? How does it differ from static equilibrium?

Short Answer

Expert verified
Dynamic equilibrium is a balanced state in a system undergoing a continuous change with no net effect, while static equilibrium is a balanced state with no change and movement.

Step by step solution

01

Identify Dynamic Equilibrium

Dynamic equilibrium refers to a state where the rate of the forward reaction is equal to the rate of the reverse reaction in a chemical process. This results in the concentrations of reactants and products remaining constant over time.
02

Explain Static Equilibrium

Static equilibrium occurs when all the forces acting upon an object are balanced, but unlike in dynamic equilibrium, there is no movement and no change over time in the properties of the system.
03

Compare Dynamic and Static Equilibrium

While both types of equilibrium involve a state of balance, dynamic equilibrium occurs with continuous change where forward and reverse reactions or processes are happening at the same rates, leading to no net change over time. In contrast, static equilibrium implies no change at all, with no movement and no ongoing processes.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Equilibrium
Chemical equilibrium is a fascinating state in which a reversible chemical reaction occurs, yet the overall concentrations of reactants and products remain unchanged. This occurs because the rate at which the reactants are converting to products is exactly balanced by the rate at which products revert back to reactants. Imagine a dance between molecules where partners (the reactants and products) swap at the same pace they are replaced, thus maintaining a consistent population on the dance floor.

It's important to understand that reaching chemical equilibrium does not mean that the reactants and products are present in equal quantities. Rather, it signifies that their rates of formation are equivalent, and this balance point can be expressed using an equilibrium constant (\( K_{eq} \)), which offers insight into the proportions of reactants to products in the equilibrium state. In the educational efforts to demystify this concept, examples often include reversible reactions, such as the synthesis of ammonia in the Haber process, and exploring how changes like pressure and temperature shift the equilibrium point, as indicated by Le Châtelier's Principle.
Static Equilibrium
Delving into the concept of static equilibrium, this scenario describes a system where all acting forces are in balance, yet, unlike dynamic equilibrium, there is no motion or change within the system. It's a bit like a perfectly balanced seesaw that remains horizontal because the people on either side are of equal weight and are not moving.

Likewise, in a static system, if you analyze a building or bridge, all the forces being applied – gravitational, tension, and compression – are in a state of balance, and thus the structure does not move. Learning about static equilibrium is crucial for students of physics and engineering as it forms the foundation for understanding how structures can be designed to withstand various forces without collapsing. To illustrate these principles, educational content might highlight the analysis of beam balances or objects at rest on inclines, emphasizing the role of forces such as friction and the normal force.
Reaction Rates
The concept of reaction rates is integral to the study of dynamic equilibrium and involves the speed at which reactants are transformed into products in a chemical reaction. Reaction rates can be influenced by various factors, such as temperature, pressure, concentration, and the presence of catalysts. To illustrate: the faster you walk, the sooner you reach your destination; similarly, the higher the reaction rate, the more quickly a reaction reaches equilibrium.

For educational content aimed at helping students grasp this topic, exercises might include calculating reaction rates from concentration versus time data, or using collision theory to explain how temperature and concentration affect the frequency and energy of collisions between molecules. One classic example is the iodine clock reaction, a visually striking illustration of chemical kinetics that can be used in the classroom to show how reaction rates can be altered by changing the concentrations of reactants or the temperature of the reaction mixture.

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Most popular questions from this chapter

Suppose that you have collected \(1.0 \mathrm{~L}\) of humid air by passing it slowly through water at \(20^{\circ} \mathrm{C}\) and into a container. Estimate the mass of water vapor in the collected air, assuming that the air is saturated with water. \(\mathrm{Ar} 20^{\circ} \mathrm{C}\), the vapor pressure of water is \(17.5\) Torr.

A solution prepared by adding \(0.50 \mathrm{~g}\) of a polymer to enough toluene (an organic solvent) to make \(200 \mathrm{~mL}\). of solution had an osmotic pressure of \(0.582\) Torr at \(20^{\circ} \mathrm{C}\). What is the molar mass of the polymer?

The carbon dioxide gas dissolved in a sample of water in a partially filled, sealed containcr has reached equilibrium with its partial pressure in the air above the solution. Explain what happens to the solubility of the \(\mathrm{CO}_{2}\) if (a) the partial pressure of the \(\mathrm{CO}_{2}\) gas is doubled by the addition of more \(\mathrm{CO}_{2} ;\) (b) the total pressure of the gas above the liquid is doubled by the addition of nitrogen.

When determining a molar mass from freczingpoint depression, it is possible to make each of the following errors (among others). In each case, predict whether the error would cause the reported molar mass to be greater or less than the actual molar mass. (a) There was dust on the balance, causing the mass of solute to appear greater than it actually was. (b) The water was measured by volume, assuming a density of \(1.00 \mathrm{~g} \cdot \mathrm{cm}^{-3}\), but the water was warmer and less dense than assumed. (c) The thermometer was not calibrated accurately, so the temperature of the freering point was actually \(0.5^{\circ} \mathrm{C}\) higher than recorded. (d) The solution was not stirred sufficiently so that not all the solute dissolved.

The following groups are found in some organic molecules. Which are hydrophilic and which are hydrophobic: (a) \(-\mathrm{OH}_{;}\)(b) \(-\mathrm{CH}_{2} \mathrm{CH}_{3}\); (c) \(-\mathrm{CONH}_{2}\); (d) \(-\mathrm{Cl}\) ?

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