Explain the effect that an increase in temperature has on each of the following properties: (a) viscosity; (b) surface tension; (c) vapor pressure; (d) evaporation rate.

Short Answer

Expert verified
An increase in temperature generally causes a decrease in the viscosity and surface tension of a liquid, while causing an increase in both vapor pressure and the evaporation rate.

Step by step solution

01

Understand the Effect of Temperature on Viscosity

An increase in temperature generally decreases the viscosity of a liquid. Viscosity is a measure of a fluid's resistance to flow. As the temperature rises, the molecules in the liquid move faster, which reduces the forces of attraction between them. This results in less resistance to flow, thus reducing the viscosity.
02

Understand the Effect of Temperature on Surface Tension

An increase in temperature tends to lower the surface tension of a liquid. Surface tension is caused by the cohesive forces between liquid molecules at the surface. When heated, these molecules have more kinetic energy and are able to overcome these cohesive forces more easily, leading to a decrease in surface tension.
03

Understand the Effect of Temperature on Vapor Pressure

An increase in temperature results in an increase in vapor pressure. Vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases at a given temperature. As temperature increases, more molecules have enough kinetic energy to escape into the vapor phase, thereby increasing vapor pressure.
04

Understand the Effect of Temperature on Evaporation Rate

An increase in temperature usually increases the evaporation rate. Evaporation is a surface phenomenon where molecules at the surface of a liquid gain enough energy to become vapor. With higher temperatures, more molecules can reach the necessary energy to evaporate, hence the rate of evaporation increases.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding How Temperature Affects Viscosity
Have you ever wondered why syrup flows more readily when heated? Viscosity, a fluid's internal resistance to flow, is greatly influenced by temperature. As temperature increases, a liquid's viscosity decreases. This is because heating the fluid causes molecules to move faster and more freely, reducing the intermolecular forces that act like 'glue' holding the molecules together. Consequently, the fluid becomes 'thinner' and flows more easily.

Consider another everyday example: motor oil in a car. During cold starts, the engine oil is thick, which makes it harder for your engine to turn over. However, as the engine warms up, the viscosity of the oil decreases, and it flows more smoothly, lubricating the engine components more effectively.
Temperature's Influence on Surface Tension
Surface tension might be a less visible property, but it's a phenomenon we encounter, for instance, when we see water beading up on a waxed car hood. The surface tension is the result of cohesive forces between adjacent molecules at the surface of a liquid. As we increase the temperature, those molecules gain kinetic energy, translating into more vigorous movement and a tendency to overcome the cohesive forces. Hence, when we heat a liquid, its surface tension decreases.

In nature, this is important for the vitality of small organisms like water striders, which rely on high surface tension to walk on water. In industrial processes like printing or painting, temperature control is crucial because surface tension affects how paints and inks spread over surfaces.
How Temperature Rise Boosts Vapor Pressure
Our day-to-day life is constantly affected by vapor pressure - it's fundamental in weather phenomena, cooking, and even in the preservation of food. Vapor pressure is essentially the pressure created by the vapor of a substance, in a state of dynamic equilibrium with its liquid or solid form. When we heat a liquid, the molecules gain the energy needed to transition into the gas phase, which translates to an increase in vapor pressure.

This concept is pivotal for understanding how pressure cookers work as they cook food faster by raising the boiling point of water. Higher vapor pressure also has implications in how we store certain chemicals or fuels that may become hazardous at elevated temperatures due to increases in their vapor pressures.
Increasing Temperature and the Evaporation Rate
Many of us appreciate a hot summer day, not just for the warmth but for the increased rate at which clothes dry. This is a practical example of how higher temperatures lead to higher evaporation rates. Evaporation, the process of a substance transitioning from a liquid into a gas, happens when molecules at the liquid's surface gain enough energy to break free into the air.

Think of a puddle after a rainstorm - on a hot day, it disappears quickly. This isn't just an incidental observation; it's an important consideration for engineers working on cooling technologies, farmers managing irrigation, or even city planners designing water features that minimize water loss. An understanding of evaporation rates is key to optimizing processes and making informed decisions related to water and energy use.

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Most popular questions from this chapter

Complete the following statements about the effect of intermolecular forces on the physical properties of a substance: (a) The higher the boiling point of a liquid, the (stronger, weaker) its intermolecular forces. (b) Substances with strong intermolecular forces have (high, low) vapor pressures. (c) Substances with strong intermolecular forces typically have (high, low) surface tensions. (d) The higher the vapor pressure of a liquid, the (stronger, weaker) its intermolecular forces. (c) Because nitrogen, \(\mathrm{N}_{2}\), has (strong, weak) intermolecular forces, it has a (high, low) critical temperature. (f) Substances with high vapor pressures have correspondingly (high, low) boiling points. (g) Because water has a relatively high boiling point, it must have (strong, weak) intermolecular forces and a correspondingly (high, low) enthalpy of vaporization.

The normal boiling point of water is \(100^{\circ} \mathrm{C}\). Suppose a cyclonic region (a region of low pressure) moves into the area. State and explain what happens to the boiling point of the water.

Bromomethane, \(\mathrm{CH}_{3} \mathrm{Br}\), and iodomethane, \(\mathrm{CH}_{3} \mathrm{I}\), form an ideal solution. The vapor pressure of bromomethane is 661 Torr and that of iodomethane is 140 Torr at \(0.0^{\circ} \mathrm{C}\). Calculate the vapor pressure of each of the following solutions and the mole fraction of each substance in the vapor phase above those solutions at \(0.0^{\circ} \mathrm{C}:\) (a) \(0.33 \mathrm{~mol}\) of bromomethane mixed with \(0.67 \mathrm{~mol}\) of iodomethane; (b) \(35.0 \mathrm{~g}\) of bromomethane mixed with \(35.0 \mathrm{~g}\) of iodomethane.

The enthalpy of solution for ammonium nitrate in water is positive. (a) Does \(\mathrm{NH}_{4} \mathrm{NO}_{3}\) dissolve endothermically or exothermically? (b) Write the chemical equation for the dissolving process. (c) Which is larger for \(\mathrm{NH}_{4} \mathrm{NO}_{3}\), the lattice enthalpy or the enthalpy of hydration?

Hexane, \(\left(\mathrm{C}_{6} \mathrm{H}_{14}\right)\) and cyclohexane \(\left(\mathrm{C}_{6} \mathrm{H}_{12}\right)\) form an ideal solution. The vapor pressure of hexane is 151 Torr and that of cyclohexane is 98 Torr at \(25.0^{\circ} \mathrm{C}\). Calculate the vapor pressure of each of the following solutions and the mole fraction of each substance in the vapor phase above those solutions: (a) \(0.2 \mathrm{~S} \mathrm{~mol} \mathrm{C}_{6} \mathrm{H}_{14}\) mixed with \(0.65 \mathrm{~mol} \mathrm{C}_{6} \mathrm{H}_{12}\) (b) \(10.0 \mathrm{~g}\) of hexane mixed with \(10.0 \mathrm{~g}\) of cyclohexane.

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