Chapter 10: Problem 30
Compare and contrast the structures of the following solids. a. diamond versus graphite b. silica versus silicates versus glass
Chapter 10: Problem 30
Compare and contrast the structures of the following solids. a. diamond versus graphite b. silica versus silicates versus glass
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Get started for freeIn each of the following groups of substances, pick the one that has the given property. Justify your answer. a. highest boiling point: HBr, Kr, or \(\mathrm{Cl}_{2}\) b. highest freezing point: \(\mathrm{H}_{2} \mathrm{O}, \mathrm{NaCl}\) , or HF c. lowest vapor pressure at $25^{\circ} \mathrm{C} : \mathrm{Cl}_{2}, \mathrm{Br}_{2},\( or \)\mathrm{I}_{2}$ d. lowest freezing point: \(\mathrm{N}_{2}, \mathrm{CO},\) or \(\mathrm{CO}_{2}\) e. lowest boiling point: \(\mathrm{CH}_{4}, \mathrm{CH}_{3} \mathrm{CH}_{3},\) or \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{3}\) f. highest boiling point: \(\mathrm{HF}, \mathrm{HCl},\) or \(\mathrm{HBr}\) g. lowest vapor pressure at $25^{\circ} \mathrm{C} : \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{3}, \mathrm{CH}_{3} \mathrm{CCH}_{3}$ or \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\)
A topaz crystal has an interplanar spacing \((d)\) of 1.36 \(\mathrm{A}\) $\left(1 \mathrm{A}=1 \times 10^{-10} \mathrm{m}\right) .$ Calculate the wavelength of the \(\mathrm{X}\) ray that should be used if $\theta=15.0^{\circ}(\text { assume } n=1)$ .
The radius of tungsten is 137 \(\mathrm{pm}\) and the density is 19.3 \(\mathrm{g} / \mathrm{cm}^{3}\) . Does elemental tungsten have a face-centered cubic structure or a body- centered cubic structure?
The CsCl structure is a simple cubic array of chloride ions with a cesium ion at the center of each cubic array (see Exercise 71 ). Given that the density of cesium chloride is 3.97 \(\mathrm{g} /\) \(\mathrm{cm}^{3},\) and assuming that the chloride and cesium ions touch along the body diagonal of the cubic unit cell, calculate the distance between the centers of adjacent \(\mathrm{Cs}^{+}\) and \(\mathrm{Cl}^{-}\) ions in the solid. Compare this value with the expected distance based on the sizes of the ions. The ionic radius of \(\mathrm{Cs}^{+}\) is \(169 \mathrm{pm},\) and the ionic radius of \(\mathrm{Cl}^{-}\) is 181 \(\mathrm{pm} .\)
The shape of the meniscus of water in a glass tube is different from that of mercury in a glass tube. Why?
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