Chapter 12: Problem 22
Individuals who suffer from lactose intolerance do not produce enough of the enzyme lactase. Explain why this is an issue.
Chapter 12: Problem 22
Individuals who suffer from lactose intolerance do not produce enough of the enzyme lactase. Explain why this is an issue.
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Get started for freeA certain substance, initially at 0.10\(M\) in solution, decomposes by second- order kinetics. If the rate constant for this process is 0.40 $\mathrm{L} / \mathrm{mol} \cdot \min$ , how much time is required for the concentration to reach 0.020 \(\mathrm{M}\) ?
At \(40^{\circ} \mathrm{C}, \mathrm{H}_{2} \mathrm{O}_{2}(a q)\) will decompose according to the following reaction: $$ 2 \mathrm{H}_{2} \mathrm{O}_{2}(a q) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(l)+\mathrm{O}_{2}(\mathrm{~g}) $$ The following data were collected for the concentration of $\mathrm{H}_{2} \mathrm{O}_{2}$ at various times. $$ \begin{array}{|cc|} \hline \begin{array}{c} \text { Time } \\ (\mathbf{s}) \end{array} & \begin{array}{c} {\left[\mathrm{H}_{2} \mathrm{O}_{2}\right]} \\ (\mathrm{mol} / \mathrm{L}) \end{array} \\ \hline 0 & 1.000 \\ \hline 2.16 \times 10^{4} & 0.500 \\ \hline 4.32 \times 10^{4} & 0.250 \\ \hline \end{array} $$ a. Calculate the average rate of decomposition of $\mathrm{H}_{2} \mathrm{O}_{2}\( between 0 and \)2.16 \times 10^{4} \mathrm{~s}$. Use this rate to calculate the average rate of production of \(\mathrm{O}_{2}(g)\) over the same time period. b. What are these rates for the time period \(2.16 \times 10^{4} \mathrm{~s}\) to \(4.32 \times 10^{4} \mathrm{~s} ?\)
Consider the reaction $$ 3 \mathrm{A}+\mathrm{B}+\mathrm{C} \longrightarrow \mathrm{D}+\mathrm{E} $$ where the rate law is defined as $$ -\frac{\Delta[\mathrm{A}]}{\Delta t}=k[\mathrm{A}]^{2}[\mathrm{B}][\mathrm{C}] $$ An experiment is carried out where $[\mathrm{B}]_{0}=[\mathrm{C}]_{0}=1.00 \mathrm{M}$ and \([\mathrm{A}]_{0}=1.00 \times 10^{-4} \mathrm{M}\) a. If after \(3.00 \min ,[\mathrm{A}]=3.26 \times 10^{-5} M,\) calculate the value of \(k .\) b. Calculate the half-life for this experiment. c. Calculate the concentration of \(B\) and the concentration of A after 10.0 min.
The rate constant \((k)\) depends on which of the following (there may be more than one answer)? a. the concentration of the reactants b. the nature of the reactants c. the temperature d. the order of the reaction Explain.
A certain substance, initially present at \(0.0800 M,\) decomposes by zero-order kinetics with a rate constant of $2.50 \times 10^{-2} \mathrm{mol} / \mathrm{L}$ . s. Calculate the time (in seconds required for the system to reach a concentration of 0.0210\(M .\)
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