Chapter 14: Problem 15
What is meant by pH? True or false: A strong acid solution always has a lower pH than a weak acid solution. Explain.
Chapter 14: Problem 15
What is meant by pH? True or false: A strong acid solution always has a lower pH than a weak acid solution. Explain.
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Get started for freeIsocyanic acid \((\mathrm{HNCO})\) can be prepared by heating sodium cyanate in the presence of solid oxalic acid according to the equation $$ 2 \mathrm{NaOCN}(s)+\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(s) \longrightarrow 2 \mathrm{HNCO}(l)+\mathrm{Na}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(s) $$ Upon isolating pure HNCO \((l),\) an aqueous solution of HNCO can be prepared by dissolving the liquid HNCO in water. What is the pH of a 100 -mL solution of HNCO prepared from the reaction of 10.0 g each of NaOCN and $\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4},$ assuming all of the HNCO produced is dissolved in solution? \(\left(K_{\mathrm{a}} \text { of HNCO }\right.\) \(=1.2 \times 10^{-4} . )\)
Calculate the percentage of pyridine $\left(\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{N}\right)\( that forms pyridinium ion, \)\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{NH}^{+},\( in a \)0.10-M$ aqueous solution of pyridine \(\left(K_{\mathrm{b}}=1.7 \times 10^{-9}\right)\)
Making use of the assumptions we ordinarily make in calculating the \(\mathrm{pH}\) of an aqueous solution of a weak acid, calculate the pH of a \(1.0 \times 10^{-6}-\mathrm{M}\) solution of hypobromous acid \(\left(\mathrm{HBrO}, K_{\mathrm{a}}=2 \times 10^{-9}\right) .\) What is wrong with your answer? Why is it wrong? Without trying to solve the problem, explain what has to be included to solve the problem correctly.
A codeine-containing cough syrup lists codeine sulfate as a major ingredient instead of codeine. The Merck Index gives $\mathrm{C}_{36} \mathrm{H}_{44} \mathrm{N}_{2} \mathrm{O}_{10} \mathrm{S}$ as the formula for codeine sulfate. Describe the composition of codeine sulfate. (See Exercise \(104 . )\) Why is codeine sulfate used instead of codeine?
Calculate the concentration of an aqueous \(\mathrm{Sr}(\mathrm{OH})_{2}\) that has \(\mathrm{pH}=10.50\) .
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