Chapter 14: Problem 63
How would you prepare 1600 \(\mathrm{mL}\) of a pH \(=1.50\) solution using concentrated \((12 M) \mathrm{HCl} ?\)
Chapter 14: Problem 63
How would you prepare 1600 \(\mathrm{mL}\) of a pH \(=1.50\) solution using concentrated \((12 M) \mathrm{HCl} ?\)
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Get started for freeHemoglobin (abbreviated Hb) is a protein that is responsible for the transport of oxygen in the blood of mammals. Each hemoglobin molecule contains four iron atoms that are the binding sites for \(\mathrm{O}_{2}\) molecules. The oxygen binding is pH- dependent. The relevant equilibrium reaction is $$ \mathrm{HbH}_{4}^{4+}(a q)+4 O_{2}(g) \rightleftharpoons \mathrm{Hb}\left(\mathrm{O}_{2}\right)_{4}(a q)+4 \mathrm{H}^{+}(a q) $$ Use Le Châtelier's principle to answer the following. a. What form of hemoglobin, HbH \(_{4}^{4+}\) or \(\mathrm{Hb}\left(\mathrm{O}_{2}\right)_{4},\) is favored in the lungs? What form is favored in the cells? b. When a person hyperventilates, the concentration of \(\mathrm{CO}_{2}\) in the blood is decreased. How does this affect the oxygen-binding equilibrium? How does breathing into a paper bag help to counteract this effect? (See Exercise \(146 .\) ) c. When a person has suffered a cardiac arrest, injection of a sodium bicarbonate solution is given. Why is this necessary? (Hint: CO, blood levels increase during cardiac arrest.)
Use Table 14.3 to help order the following bases from strongest to weakest. $$ \mathrm{NO}_{3}^{-}, \quad \mathrm{H}_{2} \mathrm{O}, \quad \mathrm{NH}_{3}, \quad \mathrm{C}_{5} \mathrm{H}_{5} \mathrm{N} $$ Also order the following acids from strongest to weakest. $$ \mathrm{HNO}_{3}, \quad \mathrm{H}_{2} \mathrm{O}, \quad \mathrm{NH}_{4}^{+}, \quad \mathrm{C}_{5} \mathrm{H}_{5} \mathrm{NH}^{+} $$
Rank the following 0.10\(M\) solutions in order of increasing \(\mathrm{pH.}\) a. HI, HF, NaF, NaI b. \(\mathrm{NH}_{4} \mathrm{Br}, \mathrm{HBr}, \mathrm{KBr}, \mathrm{NH}_{3}\) c. $C_{6} \mathrm{H}_{5} \mathrm{NH}_{3} \mathrm{NO}_{3}, \mathrm{NaNO}_{3}, \mathrm{NaOH}, \mathrm{HOC}_{6} \mathrm{H}_{5}, \mathrm{KOC}_{6} \mathrm{H}_{5}$ \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2}, \mathrm{HNO}_{3}\)
Write out the stepwise \(K_{\mathrm{a}}\) reactions for the diprotic acid \(\mathrm{H}_{2} \mathrm{SO}_{3}\)
A codeine-containing cough syrup lists codeine sulfate as a major ingredient instead of codeine. The Merck Index gives $\mathrm{C}_{36} \mathrm{H}_{44} \mathrm{N}_{2} \mathrm{O}_{10} \mathrm{S}$ as the formula for codeine sulfate. Describe the composition of codeine sulfate. (See Exercise \(104 . )\) Why is codeine sulfate used instead of codeine?
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