Chapter 19: Problem 54
The binding energy per nucleon for magnesium- 27 is $1.326 \times 10^{-12} \mathrm{J} /\( nucleon. Calculate the atomic mass of \)^{27} \mathrm{Mg}$ .
Chapter 19: Problem 54
The binding energy per nucleon for magnesium- 27 is $1.326 \times 10^{-12} \mathrm{J} /\( nucleon. Calculate the atomic mass of \)^{27} \mathrm{Mg}$ .
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Get started for freeZirconium is one of the few metals that retains its structural integrity upon exposure to radiation. The fuel rods in most nuclear reactors therefore are often made of zirconium. Answer the following questions about the redox properties of zirconium based on the half-reaction $$ \mathrm{ZrO}_{2} \cdot \mathrm{H}_{2} \mathrm{O}+\mathrm{H}_{2} \mathrm{O}+4 \mathrm{e}^{-} \longrightarrow \mathrm{Zr}+4 \mathrm{OH}^{-} \quad 8^{\circ}=-2.36 \mathrm{V} $$ a. Is zirconium metal capable of reducing water to form hydrogen gas at standard conditions? b. Write a balanced equation for the reduction of water by zirconium. c. Calculate \(\mathscr{G} \circ, \Delta G^{\circ},\) and \(K\) for the reduction of water by zirconium metal. d. The reduction of water by zirconium occurred during the accidents at Three Mile Island in \(1979 .\) The hydrogen produced was successfully vented and no chemical explosion occurred? If \(1.00 \times 10^{3} \mathrm{kg}\) Zreacts, what mass of \(\mathrm{H}_{2}\) is produced? What volume of \(\mathrm{H}_{2}\) at 1.0 \(\mathrm{atm}\) and \(1000 .^{\circ} \mathrm{C}\) is produced? e. At Chernobyl in \(1986,\) hydrogen was produced by the reaction of superheated steam with the graphite reactor core: $$ \mathrm{C}(s)+\mathrm{H}_{2} \mathrm{O}(g) \longrightarrow \mathrm{CO}(g)+\mathrm{H}_{2}(g) $$ It was not possible to prevent a chemical explosion at Chernobyl. In light of this, do you think it was a correct decision to vent the hydrogen and other radioactive gases into the atmosphere at Three Mile Island? Explain.
Much of the research on controlled fusion focuses on the problem of how to contain the reacting material. Magnetic fields appear to be the most promising mode of containment. Why is containment such a problem? Why must one resort to magnetic fields for containment?
Using the kinetic molecular theory (section \(5.6 ),\) calculate the root mean square velocity and the average kinetic energy of \(_{1}^{2} \mathrm{H}\) nuclei at a temperature of \(4 \times 10^{7} \mathrm{K}\) . (See Exercise 56 for the appropriate mass values.)
Radioactive copper-64 decays with a half-life of 12.8 days. a. What is the value of \(k\) in \(\mathrm{s}^{-1} ?\) b. A sample contains 28.0 \(\mathrm{mg}^{64} \mathrm{Cu}\) . How many decay events will be produced in the first second? Assume the atomic mass of $^{64} \mathrm{Cu}\( is 64.0 \)\mathrm{u} .$ c. A chemist obtains a fresh sample of \(^{64} \mathrm{Cu}\) and measures its radioactivity. She then determines that to do an experiment, the radioactivity cannot fall below 25\(\%\) of the initial measured value. How long does she have to do the experiment?
Technetium- 99 has been used as a radiographic agent in bone scans $(43 \mathrm{Tc} \text { is absorbed by bones). If } 43 \mathrm{Tc} \text { has a half-life of }\( 6.0 hours, what fraction of an administered dose of \)100 . \mu \mathrm{g}\( 43 \)\mathrm{Tc}$ remains in a patient's body after 2.0 days?
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