Chapter 20: Problem 1
Although the earth was formed from the same interstellar material as the sun, there is little elemental hydrogen \(\left(\mathrm{H}_{2}\right)\) in the earth's atmosphere. Explain.
Chapter 20: Problem 1
Although the earth was formed from the same interstellar material as the sun, there is little elemental hydrogen \(\left(\mathrm{H}_{2}\right)\) in the earth's atmosphere. Explain.
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Get started for freeThere are two forms of solid sulfur: rhombic and monoclinic. The stable form of sulfur at \(25^{\circ} \mathrm{C}\) is the rhombic form. Upon heating, the rhombic form converts to the monoclinic form, which is the stable form of sulfur at high temperatures. Consider the process: $$ \mathrm{S}_{\text { rhombic }}(s) \longrightarrow \mathrm{S}_{\text { monoclinic }}(s) $$ Predict the signs of \(\Delta H\) and \(\Delta S\) for this process. Which form of sulfur has the more ordered structure (has the smaller positional probability)?
What trade-offs must be made between kinetics and thermodynamics in the Haber process for the production of ammonia? How did the discovery of an appropriate catalyst make the process feasible?
There is evidence that radon reacts with fluorine to form compounds similar to those formed by xenon and fluorine. Predict the formulas of these \(\operatorname{Rn} \mathrm{F}_{x}\) compounds.
EDTA is used as a complexing agent in chemical analysis. Solutions of EDTA, usually containing the disodium salt $\mathrm{Na}_{2} \mathrm{H}_{2} \mathrm{EDTA}$ , are also used to treat heavy metal poisoning. The equilibrium constant for the following reaction is \(6.7 \times 10^{21} :\) Calculate \(\left[\mathrm{Pb}^{2+}\right]\) at equilibrium in a solution originally 0.0050 \(\mathrm{M}\) in \(\mathrm{Pb}^{2+}, 0.075 M\) in \(\mathrm{H}_{2} \mathrm{EDTA}^{2-},\) and buffered at \(\mathrm{pH}=7.00 .\)
Tin forms compounds in the \(+2\) and \(+4\) oxidation states. Therefore, when tin reacts with fluorine, two products are possible. Write balanced equations for the production of the two tin halide compounds and name them.
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