Chapter 20: Problem 12
What structural features do the molecules $\mathrm{P}_{4}, \mathrm{P}_{4} \mathrm{O}_{6},\( and \)\mathrm{P}_{4} \mathrm{O}_{10}$ have in common?
Chapter 20: Problem 12
What structural features do the molecules $\mathrm{P}_{4}, \mathrm{P}_{4} \mathrm{O}_{6},\( and \)\mathrm{P}_{4} \mathrm{O}_{10}$ have in common?
All the tools & learning materials you need for study success - in one app.
Get started for freeThe United States Public Health Service (USPHS) recommends the fluoridation of water as a means for preventing tooth decay. The recommended concentration is 1 \(\mathrm{mg} \mathrm{F}^{-} / \mathrm{L}\) . The presence of calcium ions in hard water can precipitate the added fluoride. What is the maximum molarity of calcium ions in hard water if the fluoride concentration is at the USPHS recommended level? $\left(K_{\mathrm{sp}} \text { for } \mathrm{CaF}_{2}=4.0 \times 10^{-11} .\right)$
Indium(III) phosphide is a semiconducting material that has been frequently used in lasers, light-emitting diodes (LED), and fiber-optic devices. This material can be synthesized at \(900 . \mathrm{K}\) according to the following reaction: $$ \operatorname{In}\left(\mathrm{CH}_{3}\right)_{3}(g)+\mathrm{PH}_{3}(g) \longrightarrow \operatorname{InP}(s)+3 \mathrm{CH}_{4}(g) $$ a. If 2.56 \(\mathrm{L} \operatorname{In}\left(\mathrm{CH}_{3}\right)_{3}\) at 2.00 \(\mathrm{atm}\) is allowed to react with 1.38 \(\mathrm{L} \mathrm{PH}_{3}\) at \(3.00 \mathrm{atm},\) what mass of InP(s) will be produced assuming the reaction has an 87\(\%\) yield? b. When an electric current is passed through an optoelectronic device containing InP, the light emitted has an energy of $2.03 \times 10^{-19} \mathrm{J}$ . What is the wavelength of this light and is it visible to the human eye? c. The semiconducting properties of InP can be altered by doping. If a small number of phosphorus atoms are replaced by atoms with an electron configuration of \([\mathrm{Kr}] 5 s^{2} 4 d^{10} 5 p^{4},\) is this n-type or p-type doping?
There are three known xenon fluoride covalent compounds: $\mathrm{XeF}_{2}, \mathrm{XeF}_{4},\( and \)\mathrm{XeF}_{6} .$ In general, the xenon fluoride compounds must be stored in an inert atmosphere, free of oxygen and water. Why is this the case?
Nitrous oxide \(\left(\mathrm{N}_{2} \mathrm{O}\right)\) can be produced by thermal decomposition of ammonium nitrate: $$ \mathrm{NH}_{4} \mathrm{NO}_{3}(s) \stackrel{\mathrm{heat}}{\longrightarrow} \mathrm{N}_{2} \mathrm{O}(g)+2 \mathrm{H}_{2} \mathrm{O}(l) $$ What volume of \(\mathrm{N}_{2} \mathrm{O}(g)\) collected over water at a total pressure of 94.0 \(\mathrm{kPa}\) and \(22^{\circ} \mathrm{C}\) can be produced from thermal decomposition of 8.68 $\mathrm{g} \mathrm{NH}_{4} \mathrm{NO}_{3} ?\( The vapor pressure of water at \)22^{\circ} \mathrm{C}$ is 21 torr.
Use the symbols of the elements described in the following clues to fill in the blanks that spell out the name of a famous American scientist. Although this scientist was better known as a physicist than as a chemist, the Philadelphia institute that bears his name does include a biochemistry research facility. (1) The oxide of this alkaline earth metal is amphoteric. (2) The element that makes up approximately 3.0% by mass of the human body. (3) The element having a 7\(s^{1}\) valence electron configuration. (4) This element is the alkali metal with the least negative standard reduction potential. Write its symbol in reverse order. (5) The alkali metal whose ion is more concentrated in intracellular fluids as compared with blood plasma. (6) This is the only alkali metal that reacts directly with nitrogen to make a binary compound with formula \(\mathrm{M}_{3} \mathrm{N}\). (7) This element is the first in Group 3A for which the 11 oxidation state is exhibited in stable compounds. Use only the second letter of its symbol.
What do you think about this solution?
We value your feedback to improve our textbook solutions.