Chapter 21: Problem 21
What causes high-altitude sickness, and what is high-altitude acclimatization?
Chapter 21: Problem 21
What causes high-altitude sickness, and what is high-altitude acclimatization?
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Get started for freeWhen concentrated hydrochloric acid is added to a red solution containing the \(\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}^{2+}\) complex ion, the solution turns blue as the tetrahedral \(\mathrm{CoCl}_{4}^{2-}\) complex ion forms. Explain this color change.
Acetylacetone, abbreviated acacH, is a bidentate ligand. It loses a proton and coordinates as acac \(^{-},\) as shown below, where \(\mathrm{M}\) is a transition metal: Which of the following complexes are optically active: cis-$\mathrm{Cr}(\mathrm{acac})_{2}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2},\( trans-Cr(acac) \)_{2}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2},\( and \)\mathrm{Cr}(\mathrm{acac})_{3} ?$
Oxalic acid is often used to remove rust stains. What properties of oxalic acid allow it to do this?
Qualitatively draw the crystal field splitting of the \(d\) orbitals in a trigonal planar complex ion. (Let the \(z\) axis be perpendicular to the plane of the complex.)
Draw all geometrical and linkage isomers of \(\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4}\left(\mathrm{NO}_{2}\right)_{2}\)
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