In which of the following is(are) the electron configuration(s) correct for the species indicated? a. \(\mathrm{Cu} \quad[\mathrm{Ar}] 4 s^{2} 3 d^{9}\) b. \(\mathrm{Fe}^{3+} \quad[\mathrm{Ar}] 3 d^{5}\) c. \(\mathrm{Co} \quad[\mathrm{Ar}] 4 s^{2} 3 d^{7}\) d. La \(\quad[\mathrm{Ar}] 6 s^{2} 4 f^{1}\) e. \(\mathrm{Pt}^{2+} \quad[\mathrm{Xe}] 4 f^{14} 5 d^{8}\)

Short Answer

Expert verified
#tag_title#Step 2: Calculate the electron configurations for each species.#tag_content#Using the atomic numbers, we can now write the electron configurations for each species, including charge considerations. a. Cu should have the electron configuration: \([\mathrm{Ar}] 4s^1 3d^{10}\) due to the increased stability of a filled d orbital. b. Fe³⁺ would have 3 less electrons than neutral Fe, so its electron configuration should be: \([\mathrm{Ar}] 3d^5\). c. Co should have the electron configuration: \([\mathrm{Ar}] 4s^2 3d^7\). d. La should have the electron configuration: \([\mathrm{Xe}] 6s^2 5d^1\), since it is the first member of the d-block after the f-block. e. Pt²⁺ would have 2 less electrons than neutral Pt, so its electron configuration should be: \([\mathrm{Xe}] 4f^{14} 5d^{8}\). #tag_title#Step 3: Compare calculated configurations with given configurations.#tag_content#Now, compare the calculated electron configurations with the given ones in the question. a. Given: \([\mathrm{Ar}] 4s^2 3d^9\), Correct: \([\mathrm{Ar}] 4s^1 3d^{10}\) - Incorrect b. Given: \([\mathrm{Ar}] 3d^5\), Correct: \([\mathrm{Ar}] 3d^5\) - Correct c. Given: \([\mathrm{Ar}] 4s^2 3d^7\), Correct: \([\mathrm{Ar}] 4s^2 3d^7\) - Correct d. Given: \([\mathrm{Ar}] 6s^2 4f^1\), Correct: \([\mathrm{Xe}] 6s^2 5d^1\) - Incorrect e. Given: \([\mathrm{Xe}] 4f^{14} 5d^{8}\), Correct: \([\mathrm{Xe}] 4f^{14} 5d^{8}\) - Correct Based on the comparison, options b, c, and e have the correct electron configurations.

Step by step solution

01

Find the atomic number of the given species.

In order to find the correct electron configuration, we need to know the atomic number of each species. Use the periodic table to find the atomic number of each element. Cu: Atomic Number = 29 Fe: Atomic Number = 26 Co: Atomic Number = 27 La: Atomic Number = 57 Pt: Atomic Number = 78

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