Chapter 22: Problem 108
Cows can digest cellulose, but humans can’t. Why not?
Chapter 22: Problem 108
Cows can digest cellulose, but humans can’t. Why not?
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Get started for freeAspartame, the artificial sweetener marketed under the name NutraSweet, is a methyl ester of a dipeptide: a. What two amino acids are used to prepare aspartame? b. There is concern that methanol may be produced by the decomposition of aspartame. From what portion of the molecule can methanol be produced? Write an equation for this reaction.
Polychlorinated dibenzo-p-dioxins (PCDDs) are highly toxic substances that are present in trace amounts as by-products of some chemical manufacturing processes. They have been implicated in a number of environmental incidents—for example, the chemical contamination at Love Canal and the herbicide spraying in Vietnam. The structure of dibenzo-pdioxin, along with the customary numbering convention, is The most toxic PCDD is 2,3,7,8-tetrachloro-dibenzo-p-dioxin. Draw the structure of this compound. Also draw the structures of two other isomers containing four chlorine atoms.
Esterification reactions are carried out in the presence of a strong acid such as \(\mathrm{H}_{2} \mathrm{SO}_{4} \cdot \mathrm{A}\) carboxylic acid is warmed with an alcohol, and an ester and water are formed. You may have made a fruity-smelling ester in the lab when studying organic functional groups. Name the carboxylic acid that is necessary to complete the following esterification reaction.
Alcohols are very useful starting materials for the production of many different compounds. The following conversions, starting with 1-butanol, can be carried out in two or more steps. Show the steps (reactants/catalysts) you would follow to carry out the conversions, drawing the formula for the organic product in each step. For each step, a major product must be produced. (See Exercise \(68 . )\) (Hint: In the presence of \(\mathrm{H}^{+},\) an alcohol is converted into an alkene and water. This is the exact reverse of the reaction of adding water to an alkene to form an alcohol.) $$ \begin{array}{l}{\text { a. } 1 \text { -butanol } \longrightarrow \text { butane }} \\ {\text { b. } 1 \text { -butanol } \longrightarrow 2 \text { -butanone }}\end{array} $$
Which of the following polymers would be stronger or more rigid? Explain your choices. a. The copolymer of ethylene glycol and terephthalic acid or the copolymer of \(1,2\) -diaminoethane and terephthalic acid $\left(1,2 \text { -diaminoethane }=\mathrm{NH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\right)$ b. The polymer of \(\mathrm{HO}-\left(\mathrm{CH}_{2}\right)_{6}-\mathrm{CO}_{2} \mathrm{H}\) or that of c. Polyacetylene or polyethylene (The monomer in polyacetylene is ethyne.)
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