Chapter 22: Problem 121
Draw the following incorrectly named compounds and name them correctly. a. 2-ethyl-3-methyl-5-isopropylhexane b. 2-ethyl-4-tert-butylpentane c. 3-methyl-4-isopropylpentane d. 2-ethyl-3-butyne
Chapter 22: Problem 121
Draw the following incorrectly named compounds and name them correctly. a. 2-ethyl-3-methyl-5-isopropylhexane b. 2-ethyl-4-tert-butylpentane c. 3-methyl-4-isopropylpentane d. 2-ethyl-3-butyne
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Get started for freeHow would you synthesize each of the following? a. 1,2-dibromopropane from propene b. acetone (2-propanone) from an alcohol c. tert-butyl alcohol (2-methyl-2-propanol) from an alkene (See Exercise 68.) d. propanoic acid from an alcohol
Ethyl caprate is an ester used in the manufacture of wine bouquets. It is sometimes called "cognac essence." Combustion analysis of a sample of ethyl caprate shows it to be 71.89\(\% \mathrm{C}\) , 12.13\(\%\) hydrogen, and 15.98\(\%\) O by mass. Hydrolysis (reaction with water) of the ester produces ethanol and a carboxylic acid. The molar mass of the carboxylic acid is 172 \(\mathrm{g} / \mathrm{mol}\) , and the \(\mathrm{R}\) group attached to the COOH group of the acid is a straight chain alkane. What is the structure of ethyl caprate?
Draw a structural formula for each of the following. a. 3-methylpentanoic acid b. ethyl methanoate c. methyl benzoate d. 3-chloro-2,4-dimethylhexanoic acid
Estimate \(\Delta H\) for the following reactions using bond energies given in Table \(8.5 .\) $$ 3 \mathrm{CH}_{2}=\mathrm{CH}_{2}(g)+3 \mathrm{H}_{2}(g) \rightarrow 3 \mathrm{CH}_{3}-\mathrm{CH}_{3}(g) $$ The enthalpies of formation for \(\mathrm{C}_{6} \mathrm{H}_{6}(g)\) and \(\mathrm{C}_{6} \mathrm{H}_{12}(g)\) are 82.9 and $-90.3 \mathrm{kJ} / \mathrm{mol}\( , respectively. Calculate \)\Delta H^{\circ}$ for the two reactions using standard enthalpies of formation from Appendix \( 4 .\) Account for any differences between the results obtained from the two methods.
What is polystyrene? The following processes result in a stronger polystyrene polymer. Explain why in each case. a. addition of catalyst to form syndiotactic polystyrene b. addition of 1,3-butadiene and sulfur c. producing long chains of polystyrene d. addition of a catalyst to make linear polystyrene
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