Chapter 22: Problem 30
Give the structure for each of the following. a. 4-methyl-1-pentyne b. 2,3,3-trimethyl-1-hexene c. 3-ethyl-4-decene
Chapter 22: Problem 30
Give the structure for each of the following. a. 4-methyl-1-pentyne b. 2,3,3-trimethyl-1-hexene c. 3-ethyl-4-decene
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Get started for freeDraw a structural formula for each of the following compounds. $$ \begin{array}{ll}{\text { a. } 2,2-\text { dimethylheptane }} & {\text { c. } 3,3 \text { -dimethylheptane }} \\ {\text { b. } 2,3 \text { -dimethylheptane }} & {\text { d. } 2,4 \text { -dimethylheptane }}\end{array} $$
There are three isomers of dichlorobenzene, one of which has now replaced naphthalene as the main constituent of mothballs. a. Identify the ortho, the meta, and the para isomers of dichlorobenzene. b. Predict the number of isomers for trichlorobenzene. c. It turns out that the presence of one chlorine atom on a benzene ring will cause the next substituent to add ortho or para to the first chlorine atom on the benzene ring. What does this tell you about the synthesis of m-dichlorobenzene? d. Which of the isomers of trichlorobenzene will be the hardest to prepare?
Cis-trans isomerism is also possible in molecules with rings. Draw the cis and trans isomers of \(1,2\) -dimethylcyclohexane. In Exercise \(43,\) you drew all of the noncyclic structural and geometrical isomers of $\mathrm{C}_{4} \mathrm{H}_{7} \mathrm{F}$ . Now draw the cyclic structural and geometrical isomers of \(\mathrm{C}_{4} \mathrm{H}_{7} \mathrm{F}\) .
Oxygen is carried from the lungs to tissues by the protein hemoglobin in red blood cells. Sickle cell anemia is a disease resulting from abnormal hemoglobin molecules in which a valine is substituted for a single glutamic acid in normal hemoglobin. How might this substitution affect the structure of hemoglobin?
In general terms, what does the secondary structure of a protein represent? How is the secondary structure of a protein related to its function?
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