Aluminum reacts with bromine, producing aluminum bromide: $$ 2 \mathrm{Al}(s)+3 \mathrm{Br}_{2}(l) \rightarrow 2 \mathrm{AlBr}_{3}(s) $$ In a certain experiment, 20.0 \(\mathrm{mL}\) of bromine (density \(=\) 3.10 \(\mathrm{g} / \mathrm{mL}\) ) was reacted with excess aluminum to yield 50.3 \(\mathrm{g}\) of aluminum bromide. What is the percent yield for this experiment?

Short Answer

Expert verified
The percent yield for this experiment is approximately 73.0%.

Step by step solution

01

Calculate the mass of bromine used

To calculate the mass of bromine used, we will multiply the given volume (20.0 mL) by the density (3.10 g/mL): Mass of bromine = (20.0 mL) * (Density) \(=20.0\,\mathrm{mL}\times3.10\,\frac{\mathrm{g}}{\mathrm{mL}}=62.0\,\mathrm{g}\) So, the mass of bromine used in the reaction is 62.0 g.
02

Calculate the moles of bromine

We have to convert the mass of bromine into moles using the molar mass of bromine. The molar mass of Br2 is approximately 159.8 g/mol. Moles of bromine = mass / molar mass \(\frac{62.0\,\mathrm{g}}{159.8\,\frac{\mathrm{g}}{\mathrm{mol}}}\approx0.388\,\mathrm{mol}\) So we have 0.388 moles of bromine.
03

Calculate the moles of aluminum bromide that can theoretically be produced

Using the reaction stoichiometry, 3 moles of bromine react with 2 moles of aluminum to produce 2 moles of aluminum bromide. Thus, to calculate the moles of aluminum bromide that can theoretically be produced, we can use a mole-to-mole ratio. Moles of aluminum bromide = Moles of bromine * (2 / 3) \(= 0.388\,\mathrm{mol}\times \frac{2}{3}\approx 0.2587\,\mathrm{mol}\) So, approximately 0.2587 moles of aluminum bromide can theoretically be produced.
04

Calculate the theoretical mass of aluminum bromide

We have to convert the moles of aluminum bromide back into mass using the molar mass of aluminum bromide, which is approximately 266.7 g/mol. Theoretical mass of aluminum bromide = Moles of aluminum bromide * molar mass \(= 0.2587\,\mathrm{mol}\times 266.7\,\frac{\mathrm{g}}{\mathrm{mol}} \approx 68.9\,\mathrm{g}\) So, the theoretical mass of aluminum bromide is 68.9 g.
05

Calculate the percent yield of the reaction

Now that we have the actual mass of aluminum bromide really produced (50.3 g) and the theoretical mass of aluminum bromide that could be produced (68.9 g), we can calculate the percent yield. Percent yield = (Actual mass / Theoretical mass) * 100 \(\frac{50.3\,\mathrm{g}}{68.9\,\mathrm{g}} \times100\approx73.0\%\) So, the percent yield for this experiment is approximately 73.0%.

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