Sulfur dioxide gas reacts with sodium hydroxide to form sodium sulfite and water. The unbalanced chemical equation for this reaction is given below: $$ \mathrm{SO}_{2}(g)+\mathrm{NaOH}(s) \longrightarrow \mathrm{Na}_{2} \mathrm{SO}_{3}(s)+\mathrm{H}_{2} \mathrm{O}(l) $$ Assuming you react 38.3 g sulfur dioxide with 32.8 g sodium hydroxide and assuming that the reaction goes to completion, calculate the mass of each product formed.

Short Answer

Expert verified
The mass of sodium sulfite (Na2SO3) formed is 75.3 g, and the mass of water (H2O) formed is 10.8 g.

Step by step solution

01

Balance the chemical equation

First, balance the chemical equation for this reaction: $$ \mathrm{SO}_{2}(g) + 2 \mathrm{NaOH}(s) \longrightarrow \mathrm{Na}_{2}\mathrm{SO}_{3}(s) + \mathrm{H}_{2} \mathrm{O}(l) $$ Now, we have the balanced chemical equation.
02

Convert the given masses of reactants to moles

We are given 38.3 g of sulfur dioxide (SO2) and 32.8 g of sodium hydroxide (NaOH). Convert these masses to moles using their molar masses: Molar mass of SO2: \(1 \cdot 32.1 \thinspace g/mol + 2 \cdot 16.0 \thinspace g/mol = 64.1 \thinspace g/mol\) Moles of SO2: \(\frac{38.3 \thinspace g}{64.1 \thinspace g/mol} = 0.597 \thinspace mol\) Molar mass of NaOH: \(1 \cdot 22.99 \thinspace g/mol + 1 \cdot 15.999 \thinspace g/mol + 1 \cdot 1.00784 \thinspace g/mol = 39.997 \thinspace g/mol\) Moles of NaOH: \(\frac{32.8 \thinspace g}{39.997 \thinspace g/mol} = 0.820 \thinspace mol\)
03

Use stoichiometry to find the limiting reactant

Using the balanced equation, we can determine the limiting reactant by comparing the mole ratios of the reactants: Mole ratio of SO2 to NaOH: \(\frac{0.597 \thinspace mol}{0.820 \thinspace mol} = 0.728\) Since the balanced equation requires a 1:2 ratio of SO2 to NaOH, and the actual mole ratio is less than 1, this means that SO2 is the limiting reactant.
04

Calculate the moles of products formed

Using the stoichiometry from the balanced equation: Moles of Na2SO3: \(0.597 \thinspace mol \cdot \frac{1 \thinspace mol \thinspace Na_{2}SO_{3}}{1 \thinspace mol \thinspace SO_{2}} = 0.597 \thinspace mol\) Moles of H2O: \(0.597 \thinspace mol \cdot \frac{1 \thinspace mol \thinspace H_{2}O}{1 \thinspace mol \thinspace SO_{2}} = 0.597 \thinspace mol\).
05

Convert moles of products to mass

Finally, convert the moles of each product formed to mass using their molar masses: Mass of Na2SO3: \(0.597 \thinspace mol \cdot 126.05 \thinspace g/mol = 75.3 \thinspace g\) Mass of H2O: \(0.597 \thinspace mol \cdot 18.015 \thinspace g/mol = 10.8 \thinspace g\) Hence, 75.3 g of sodium sulfite (Na2SO3) and 10.8 g of water (H2O) are formed as products.

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