A sample of urea contains $1.121 \mathrm{g} \mathrm{N}, 0.161 \mathrm{g} \mathrm{H}, 0.480 \mathrm{g} \mathrm{C}\( and 0.640 \)\mathrm{g}$ O. What is the empirical formula of urea?

Short Answer

Expert verified
The empirical formula of urea is \( \text{NH}_2\text{CO} \).

Step by step solution

01

Convert grams to moles

We have the grams for each element as follows: - Nitrogen (N): 1.121 g - Hydrogen (H): 0.161 g - Carbon (C): 0.480 g - Oxygen (O): 0.640 g Use the molar mass of each element to convert grams to moles: - Moles of N = \( \frac{1.121 \text{ g}}{14.01 \text{ g/mol}} \) - Moles of H = \( \frac{0.161 \text{ g}}{1.01 \text{ g/mol}} \) - Moles of C = \( \frac{0.480 \text{ g}}{12.01 \text{ g/mol}} \) - Moles of O = \( \frac{0.640 \text{ g}}{16.00 \text{ g/mol}} \)
02

Calculate the mole ratios

Now that we have the moles for each element, we will calculate the mole ratios. - Moles of N = \( \frac{1.121}{14.01} = 0.080 \) - Moles of H = \( \frac{0.161}{1.01} = 0.160 \) - Moles of C = \( \frac{0.480}{12.01} = 0.040 \) - Moles of O = \( \frac{0.640}{16.00} = 0.040 \)
03

Determine the simplest whole-number ratio

Next, we need to derive the simplest whole-number ratio between the mole ratios calculated in Step 2. Divide each mole ratio by the smallest one, which in this case is 0.040 (moles of Carbon and Oxygen): - Ratio for N = \( \frac{0.080}{0.040} = 2 \) - Ratio for H = \( \frac{0.160}{0.040} = 4 \) - Ratio for C = \( \frac{0.040}{0.040} = 1 \) - Ratio for O = \( \frac{0.040}{0.040} = 1 \)
04

Write the empirical formula

Lastly, we will write the empirical formula using the simplest whole number ratio obtained in Step 3: The empirical formula of urea is: \( \text{NH}_2\text{CO} \)

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