A solution is prepared by dissolving 0.6706 g oxalic acid \(\left(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}\right)\) in enough water to make 100.0 \(\mathrm{mL}\) of solution. A 10.00-mL aliquot (portion) of this solution is then diluted to a final volume of 250.0 mL. What is the final molarity of the oxalic acid solution?

Short Answer

Expert verified
The final molarity of the oxalic acid solution can be calculated using the following steps: 1. Calculate moles of oxalic acid in the initial 100 mL solution: \(Moles = \frac{0.6706\ g}{90.04\ g/mol} \approx 0.00745\ mol\). 2. Determine the concentration of oxalic acid in the initial 100 mL solution: \(Molarity = \frac{0.00745\ mol}{0.1\ L} = 0.0745\ M\). 3. Calculate moles of oxalic acid in the 10 mL aliquot: \(Moles\ in\ aliquot = 0.0745\ M \times 0.01\ L = 0.000745\ mol\). 4. Determine the final molarity of oxalic acid in the final 250 mL diluted solution: \(Final\ Molarity = \frac{0.000745\ mol}{0.25\ L} = 0.00298\ M\). Thus, the final molarity of the oxalic acid solution is approximately \(0.00298\ M\).

Step by step solution

01

1. Calculate the moles of oxalic acid in the initial 100 mL solution.

To determine the moles of oxalic acid, we'll use the molecular weight of oxalic acid, and the given mass: Molecular weight of oxalic acid, H2C2O4 is \(2 \times 1.01 (H) + 2 \times 12.01 (C) + 4 \times 16.00 (O) = 90.04\ g/mol\). Given mass of oxalic acid is 0.6706 g. Now, use the formula: Moles = \(\frac{Mass}{Molecular\ weight}\) Moles = \(\frac{0.6706}{90.04}\)
02

2. Determine the concentration of oxalic acid in the initial 100 mL solution.

Since we now have the moles of oxalic acid, we can find the initial concentration using the volume of the initial 100 mL solution: Molarity = \(\frac{Moles}{Volume(in\ L)}\) Molarity = \(\frac{Moles}{0.1\ L}\)
03

3. Calculate the moles of oxalic acid in the 10 mL aliquot.

The aliquot is a portion of the original solution, with the same concentration. To find the moles of oxalic acid in the aliquot, multiply the concentration from step 2 by the aliquot volume in liters: Moles in aliquot = (Molarity in initial solution) \(\times\) (Volume of aliquot)
04

4. Determine the final molarity of oxalic acid in the final 250 mL diluted solution.

Now, we'll find the final molarity by dividing the moles of oxalic acid in the aliquot by the final volume of the diluted solution (250 mL): Final Molarity = \(\frac{Moles\ in\ aliquot}{Final\ volume(in\ L)}\) Final Molarity = \(\frac{Moles\ in\ aliquot}{0.25\ L}\)

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