You are given a 1.50-g mixture of sodium nitrate and sodium chloride. You dissolve this mixture into 100 mL of water and then add an excess of 0.500 M silver nitrate solution. You produce a white solid, which you then collect, dry, and measure. The white solid has a mass of 0.641 g. a. If you had an extremely magnified view of the solution (to the atomic- molecular level), list the species you would see (include charges, if any). b. Write the balanced net ionic equation for the reaction that produces the solid. Include phases and charges. c. Calculate the mass percent of sodium chloride in the original unknown mixture.

Short Answer

Expert verified
The species present in the solution include Na⁺ (aq), NO₃⁻ (aq), Cl⁻ (aq), and Ag⁺ (aq). The balanced net ionic equation for the reaction is \(Ag^+(aq) + Cl^-(aq) \rightarrow AgCl(s)\). The mass percent of sodium chloride in the original unknown mixture is 17.4%.

Step by step solution

01

Identify the species present in the solution (Question a)

When the sodium nitrate (NaNO₃) and sodium chloride (NaCl) mixture is dissolved in water, we would observe the following species, including their charges: 1. Na⁺ (aq) - sodium ions 2. NO₃⁻ (aq) - nitrate ions 3. Cl⁻ (aq) - chloride ions Additionally, once we add the silver nitrate (AgNO₃) solution, we would also observe: 4. Ag⁺ (aq) - silver ions
02

Write the balanced net ionic equation (Question b)

The reaction that takes place is between silver ions (Ag⁺) and chloride ions (Cl⁻) to form an insoluble precipitate, silver chloride (AgCl). The balanced net ionic equation, including phases and charges, is: \( \newline Ag^+(aq) + Cl^-(aq) \rightarrow AgCl(s) \newline \)
03

Calculate the mass percent of sodium chloride (Question c)

First, we need to calculate the number of moles of silver chloride formed using its mass: Mass of AgCl = 0.641 g Molar mass of AgCl = 107.87 g/mol (Ag) + 35.45 g/mol (Cl) = 143.32 g/mol Number of moles of AgCl = (mass of AgCl)/(molar mass of AgCl) Number of moles of AgCl = (0.641 g)/(143.32 g/mol) = 0.00447 mol Since one mole of silver chloride is formed per mole of chloride ion, the number of moles of sodium chloride is equal to that of silver chloride: Number of moles of NaCl = 0.00447 mol Now we can calculate the mass of sodium chloride originally present in the mixture: Molar mass of NaCl = 22.99 g/mol (Na) + 35.45 g/mol (Cl) = 58.44 g/mol Mass of NaCl = (number of moles of NaCl) × (molar mass of NaCl) Mass of NaCl = (0.00447 mol) × (58.44 g/mol) = 0.261 g Finally, we can find the mass percent of sodium chloride in the original mixture: Mass percent of NaCl = (mass of NaCl)/(total mass of the mixture) × 100 Mass percent of NaCl = (0.261 g)/(1.50 g) × 100 = 17.4 % So, the mass percent of sodium chloride in the original unknown mixture is 17.4%.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Balance the following oxidation–reduction reactions that occur in acidic solution using the half-reaction method. a. $\mathrm{Cu}(s)+\mathrm{NO}_{3}^{-}(a q) \rightarrow \mathrm{Cu}^{2+}(a q)+\mathrm{NO}(g)$ b. $\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}(a q)+\mathrm{Cl}^{-}(a q) \rightarrow \mathrm{Cr}^{3+}(a q)+\mathrm{Cl}_{2}(g)$ c. $\mathrm{Pb}(s)+\mathrm{PbO}_{2}(s)+\mathrm{H}_{2} \mathrm{SO}_{4}(a q) \rightarrow \mathrm{PbSO}_{4}(s)$ d. $\mathrm{Mn}^{2+}(a q)+\mathrm{NaBiO}_{3}(s) \rightarrow \mathrm{Bi}^{3+}(a q)+\mathrm{MnO}_{4}-(a q)$ e. $\mathrm{H}_{3} \mathrm{AsO}_{4}(a q)+\mathrm{Zn}(s) \rightarrow \mathrm{AsH}_{3}(g)+\mathrm{Zn}^{2+}(a q)$

What mass of barium sulfate can be produced when 100.0 mL of a 0.100-M solution of barium chloride is mixed with 100.0 mL of a 0.100-M solution of iron(III) sulfate?

Chlorine gas was first prepared in 1774 by C. W. Scheele by oxidizing sodium chloride with manganese(IV) oxide. The reaction is $$\mathrm{NaCl}(a q)+\mathrm{H}_{2} \mathrm{SO}_{4}(a q)+\mathrm{MnO}_{2}(s) \longrightarrow \mathrm{Na}_{2} \mathrm{SO}_{4}(a q)+\mathrm{MnCl}_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(l)+\mathrm{Cl}_{2}(g)$$ Balance this equation.

The units of parts per million (ppm) and parts per billion (ppb) are commonly used by environmental chemists. In general, 1 ppm means 1 part of solute for every \(10^{6}\) parts of solution. Mathematically, by mass: $$\mathrm{ppm}=\frac{\mu \mathrm{g} \text { solute }}{\mathrm{g} \text { solution }}=\frac{\mathrm{mg} \text { solute }}{\mathrm{kg} \text { solution }}$$ In the case of very dilute aqueous solutions, a concentration of 1.0 \(\mathrm{ppm}\) is equal to 1.0\(\mu \mathrm{g}\) of solute per 1.0 \(\mathrm{mL}\) , which equals 1.0 \(\mathrm{g}\) solution. Parts per billion is defined in a similar fashion. Calculate the molarity of each of the following aqueous solutions. a. 5.0 \(\mathrm{ppb} \mathrm{Hg}\) in \(\mathrm{H}_{2} \mathrm{O}\) b. 1.0 \(\mathrm{ppb} \mathrm{CHCl}_{3}\) in \(\mathrm{H}_{2} \mathrm{O}\) c. 10.0 \(\mathrm{ppm}\) As in \(\mathrm{H}_{2} \mathrm{O}\) d. 0.10 $\mathrm{ppm} \mathrm{DDT}\left(\mathrm{C}_{14} \mathrm{H}_{9} \mathrm{C} 1_{5}\right)\( in \)\mathrm{H}_{2} \mathrm{O}$

Assign oxidation states for all atoms in each of the following compounds. a. $\mathrm{UO}_{2}^{2+} \quad \quad f. \mathrm{Mg}_{2} \mathrm{P}_{2} \mathrm{O}_{7}$ b. $\mathrm{As}_{2} \mathrm{O}_{3} \quad \quad g. \mathrm{Na}_{2} \mathrm{P}_{2} \mathrm{O}_{3}$ c. \(\mathrm{NaBiO}_{3} \quad h. \mathrm{Hg}_{2} \mathrm{Cl}_{2}\) d. $\mathrm{As}_{4} \quad\quad \quad i. \mathrm{Ca}\left(\mathrm{NO}_{3}\right)_{2}$ e. \(\mathrm{HAsO}_{2}\)

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free