Chapter 4: Problem 81
What volume of 0.0200 M calcium hydroxide is required to neutralize 35.00 mL of 0.0500 M nitric acid?
Chapter 4: Problem 81
What volume of 0.0200 M calcium hydroxide is required to neutralize 35.00 mL of 0.0500 M nitric acid?
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Get started for freeIt took \(25.06 \pm 0.05 \mathrm{mL}\) of a sodium hydroxide solution to titrate a 0.4016-g sample of KHP (see Exercise 83). Calculate the concentration and uncertainty in the concentration of the sodium hydroxide solution. (See Appendix 1.5.) Neglect any uncertainty in the mass
The units of parts per million (ppm) and parts per billion (ppb) are commonly used by environmental chemists. In general, 1 ppm means 1 part of solute for every \(10^{6}\) parts of solution. Mathematically, by mass: $$\mathrm{ppm}=\frac{\mu \mathrm{g} \text { solute }}{\mathrm{g} \text { solution }}=\frac{\mathrm{mg} \text { solute }}{\mathrm{kg} \text { solution }}$$ In the case of very dilute aqueous solutions, a concentration of 1.0 \(\mathrm{ppm}\) is equal to 1.0\(\mu \mathrm{g}\) of solute per 1.0 \(\mathrm{mL}\) , which equals 1.0 \(\mathrm{g}\) solution. Parts per billion is defined in a similar fashion. Calculate the molarity of each of the following aqueous solutions. a. 5.0 \(\mathrm{ppb} \mathrm{Hg}\) in \(\mathrm{H}_{2} \mathrm{O}\) b. 1.0 \(\mathrm{ppb} \mathrm{CHCl}_{3}\) in \(\mathrm{H}_{2} \mathrm{O}\) c. 10.0 \(\mathrm{ppm}\) As in \(\mathrm{H}_{2} \mathrm{O}\) d. 0.10 $\mathrm{ppm} \mathrm{DDT}\left(\mathrm{C}_{14} \mathrm{H}_{9} \mathrm{C} 1_{5}\right)\( in \)\mathrm{H}_{2} \mathrm{O}$
One of the classic methods for determining the manganese content in steel involves converting all the manganese to the deeply colored permanganate ion and then measuring the absorption of light. The steel is first dissolved in nitric acid, producing the manganese(II) ion and nitrogen dioxide gas. This solution is then reacted with an acidic solution containing the periodate ion; the products are the permanganate and iodate ions. Write balanced chemical equations for both of these steps.
Separate samples of a solution of an unknown soluble ionic compound are treated with \(\mathrm{KCl}, \mathrm{Na}_{2} \mathrm{SO}_{4},\) and \(\mathrm{NaOH}\) . A precipitate forms only when $\mathrm{Na}_{2} \mathrm{SO}_{4}$ is added. Which cations could be present in the unknown soluble ionic compound?
Many oxidation–reduction reactions can be balanced by inspection. Try to balance the following reactions by inspection. In each reaction, identify the substance reduced and the substance oxidized. a. $\mathrm{Al}(s)+\mathrm{HCl}(a q) \rightarrow \mathrm{AlCl}_{3}(a q)+\mathrm{H}_{2}(g)$ b. $\mathrm{CH}_{4}(g)+\mathrm{S}(s) \rightarrow \mathrm{CS}_{2}(l)+\mathrm{H}_{2} \mathrm{S}(g)$ c. $\mathrm{C}_{3} \mathrm{H}_{8}(g)+\mathrm{O}_{2}(g) \rightarrow \mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(i)$ d. $\mathrm{Cu}(s)+\mathrm{Ag}^{+}(a q) \rightarrow \mathrm{Ag}(s)+\mathrm{Cu}^{2+}(a q)$
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