Chapter 5: Problem 12
If you have any two gases in different containers that are the same size at the same pressure and same temperature, what is true about the moles of each gas? Why is this true?
Chapter 5: Problem 12
If you have any two gases in different containers that are the same size at the same pressure and same temperature, what is true about the moles of each gas? Why is this true?
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Get started for freeSilane, SiH, , is the silicon analogue of methane, \(\mathrm{CH}_{4}\) . It is prepared industrially according to the following equations: $$\begin{array}{c}{\mathrm{Si}(s)+3 \mathrm{HCl}(g) \longrightarrow \mathrm{HSiCl}_{3}(l)+\mathrm{H}_{2}(g)} \\ {4 \mathrm{HSiCl}_{3}(l) \longrightarrow \mathrm{SiH}_{4}(g)+3 \mathrm{SiCl}_{4}(l)}\end{array}$$ a. If \(156 \mathrm{mL}\) \(\mathrm{HSiCl}_{3} (d=1.34 \mathrm{g} / \mathrm{mL})\) is isolated when 15.0 \(\mathrm{L}\) \(\mathrm{HCl}\) at 10.0 \(\mathrm{atm}\) and \(35^{\circ} \mathrm{C}\) is used, what is the percent yield of \(\mathrm{HSiCl}_{3} ?\) b. When \(156 \mathrm{HSiCl}_{3}\) is heated, what volume of \(\mathrm{SiH}_{4}\) at 10.0 \(\mathrm{atm}\) and \(35^{\circ} \mathrm{C}\) will be obtained if the percent yield of the reaction is 93.1\(\% ?\)
One of the chemical controversies of the nineteenth century concerned the element beryllium (Be). Berzelius originally claimed that beryllium was a trivalent element (forming \(\mathrm{Be}^{3+}\) ions) and that it gave an oxide with the formula \(\mathrm{Be}_{2} \mathrm{O}_{3}\) . This resulted in a calculated atomic mass of 13.5 for beryllium. In formulating his periodic table, Mendeleev proposed that beryllium was divalent (forming \(\mathrm{Be}^{2+}\) ions) and that it gave an oxide with the formula BeO. This assumption gives an atomic mass of \(9.0 .\) In \(1894,\) A. Combes (Comptes Rendus \(1894,\) p. 1221 ) reacted beryllium with the anion $C_{5} \mathrm{H}_{7} \mathrm{O}_{2}^{-}$ and measured the density of the gaseous product. Combes's data for two different experiments are as follows: $$\begin{array}{lll}{\text { Mass }} & {0.2022 \mathrm{g}} & {0.2224 \mathrm{g}} \\ {\text { Volume }} & {22.6 \mathrm{cm}^{3}} & {26.0 \mathrm{cm}^{3}} \\ {\text { Temperature }} & {13^{\circ} \mathrm{C}} & {17^{\circ} \mathrm{C}} \\ {\text { Pressure }} & {765.2 \mathrm{mm} \mathrm{Hg}} & {764.6 \mathrm{mm}}\end{array}$$ If beryllium is a divalent metal, the molecular formula of the product will be \(\mathrm{Be}\left(\mathrm{C}_{5} \mathrm{H}_{7} \mathrm{O}_{2}\right)_{2} ;\) if it is trivalent, the formula will be $\mathrm{Be}\left(\mathrm{C}_{5} \mathrm{H}_{7} \mathrm{O}_{2}\right)_{3} .$ Show how Combes's data help to confirm that beryllium is a divalent metal.
One way of separating oxygen isotopes is by gaseous diffusion of carbon monoxide. The gaseous diffusion process behaves like an effusion process. Calculate the relative rates of effusion of $^{12} \mathrm{C}^{16} \mathrm{O},^{12} \mathrm{C}^{17} \mathrm{O},\( and \)^{12} \mathrm{C}^{18} \mathrm{O} .$ Name some advantages and disadvantages of separating oxygen isotopes by gaseous diffusion of carbon dioxide instead of carbon monoxide.
Silicon tetrachloride \(\left(\mathrm{SiCl}_{4}\right)\) and trichlorosilane \(\left(\mathrm{SiHCl}_{3}\right)\) are both starting materials for the production of electronics-grade silicon. Calculate the densities of pure \(\mathrm{SiCl}_{4}\) and pure \(\mathrm{SiHCl}_{4}\) vapor at $85^{\circ} \mathrm{C}$ and 635 torr.
Hydrogen azide, \(\mathrm{HN}_{3},\) decomposes on heating by the following unbalanced equation: $$\mathrm{HN}_{3}(g) \longrightarrow \mathrm{N}_{2}(g)+\mathrm{H}_{2}(g)$$ If 3.0 atm of pure \(\mathrm{HN}_{3}(g)\) is decomposed initially, what is the final total pressure in the reaction container? What are the partial pressures of nitrogen and hydrogen gas? Assume the volume and temperature of the reaction container are constant.
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