Chapter 5: Problem 17
How does Dalton’s law of partial pressures help us with our model of ideal gases? That is, what postulates of the kinetic molecular theory does it support?
Chapter 5: Problem 17
How does Dalton’s law of partial pressures help us with our model of ideal gases? That is, what postulates of the kinetic molecular theory does it support?
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Get started for freeSilane, SiH, , is the silicon analogue of methane, \(\mathrm{CH}_{4}\) . It is prepared industrially according to the following equations: $$\begin{array}{c}{\mathrm{Si}(s)+3 \mathrm{HCl}(g) \longrightarrow \mathrm{HSiCl}_{3}(l)+\mathrm{H}_{2}(g)} \\ {4 \mathrm{HSiCl}_{3}(l) \longrightarrow \mathrm{SiH}_{4}(g)+3 \mathrm{SiCl}_{4}(l)}\end{array}$$ a. If \(156 \mathrm{mL}\) \(\mathrm{HSiCl}_{3} (d=1.34 \mathrm{g} / \mathrm{mL})\) is isolated when 15.0 \(\mathrm{L}\) \(\mathrm{HCl}\) at 10.0 \(\mathrm{atm}\) and \(35^{\circ} \mathrm{C}\) is used, what is the percent yield of \(\mathrm{HSiCl}_{3} ?\) b. When \(156 \mathrm{HSiCl}_{3}\) is heated, what volume of \(\mathrm{SiH}_{4}\) at 10.0 \(\mathrm{atm}\) and \(35^{\circ} \mathrm{C}\) will be obtained if the percent yield of the reaction is 93.1\(\% ?\)
Equal moles of sulfur dioxide gas and oxygen gas are mixed in a flexible reaction vessel and then sparked to initiate the formation of gaseous sulfur trioxide. Assuming that the reaction goes to completion, what is the ratio of the final volume of the gas mixture to the initial volume of the gas mixture if both volumes are measured at the same temperature and pressure?
Small quantities of hydrogen gas can be prepared in the laboratory by the addition of aqueous hydrochloric acid to metallic zinc. $$\mathrm{Zn}(s)+2 \mathrm{HCl}(a q) \longrightarrow \mathrm{ZnCl}_{2}(a q)+\mathrm{H}_{2}(g)$$ Typically, the hydrogen gas is bubbled through water for collection and becomes saturated with water vapor. Suppose 240. mL of hydrogen gas is collected at \(30 .^{\circ} \mathrm{C}\) and has a total pressure of 1.032 atm by this process. What is the partial pressure of hydrogen gas in the sample? How many grams of zinc must have reacted to produce this quantity of hydrogen? (The vapor pressure of water is 32 torr at \(30 .^{\circ} \mathrm{C}\).)
\(\mathrm{N}_{2} \mathrm{O}\) is a gas commonly used to help sedate patients in medicine and dentistry due to its mild anesthetic and analgesic properties; it is also nonflammable. If a cylinder of \(\mathrm{N}_{2} \mathrm{O}\) is at 10.5 atm and has a volume of 5.00 \(\mathrm{L}\) at \(298 \mathrm{K},\) how many moles of \(\mathrm{N}_{2} \mathrm{O}\) gas are present? The gas from the cylinder is emptied into a large balloon at 745 torr. What is the volume of the balloon at 298 \(\mathrm{K}\) ?
We state that the ideal gas law tends to hold best at low pressures and high temperatures. Show how the van der Waals equation simplifies to the ideal gas law under these conditions
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