How does Dalton’s law of partial pressures help us with our model of ideal gases? That is, what postulates of the kinetic molecular theory does it support?

Short Answer

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Dalton's Law of Partial Pressures supports the first and third postulates of the Kinetic Molecular Theory. It demonstrates that individual gases in a mixture behave independently, as each gas exerts pressure on the container walls independently (Postulate 1) and their contributions to the total pressure are unaffected by the presence of other gases (Postulate 3). Thus, the total pressure of a gas mixture can be determined by summing the partial pressures of its individual components.

Step by step solution

01

Understanding Dalton's Law of Partial Pressures

Dalton's Law of Partial Pressures states that in a mixture of non-reacting gases, the total pressure exerted is equal to the sum of the partial pressures of individual gases. Mathematically, it is expressed as: \[P_{total} = P_1 + P_2 + P_3 +...+ P_n\] Where \(P_{total}\) is the total pressure of the gas mixture, and \(P_1, P_2, P_3,..., P_n\) are the partial pressures of individual gases in the mixture.
02

Understanding the Kinetic Molecular Theory

The Kinetic Molecular Theory is a model which describes the behavior of ideal gases. The theory is based on several postulates, which include: 1. Gases consist of a large number of particles (atoms or molecules) that are in constant random motion. 2. The volume occupied by the gas particles themselves is negligible compared to the volume of the container. 3. Gas particles are neither attracted nor repelled by each other and their collisions are perfectly elastic. 4. The average kinetic energy of gas particles is directly proportional to the temperature of the gas.
03

Relating Dalton's Law of Partial Pressures to the Kinetic Molecular Theory

Dalton's Law of Partial Pressures supports the following postulates of the Kinetic Molecular Theory: Postulate 1: The constant random motion of gas particles in a mixture means that each gas exerts pressure on the container walls independently. This justifies the additivity of the partial pressures in Dalton's Law. Postulate 3: Since gas particles in a mixture are neither attracted nor repelled by each other, each gas behaves independently and its contribution to the total pressure is unaffected by the presence of other gases. Therefore, Dalton's Law of Partial Pressures supports the first and third postulates of the Kinetic Molecular Theory by showing that individual gases in a mixture behave independently and that their properties can be added together to determine the properties of the mixture as a whole.

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