Ideal gas particles are assumed to be volume less and to neither attract nor repel each other. Why are these assumptions crucial to the validity of Dalton’s law of partial pressures?

Short Answer

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The assumptions of ideal gas particles being volumeless and having no interactions are crucial to the validity of Dalton's Law of Partial Pressures because they simplify the behavior of gas particles, allowing scientists to predict and calculate gas properties. By assuming gas particles have no volume and interactions, we can treat each particle independently and simply add their partial pressures together, without any complications due to their size or interaction, to get the total pressure as described by Dalton's Law: \(P_{total} = P_1 + P_2 + \cdots + P_n\). Without these assumptions, accurately predicting the total pressures of mixed gases using Dalton's Law would be much more difficult.

Step by step solution

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1. Understanding Ideal Gas Assumptions

The Ideal Gas Law (PV = nRT) is based on two key assumptions: (a) gas particles have no volume compared to the space between them, and (b) gas particles have no interactions with each other (neither attractive nor repulsive forces). These assumptions simplify the behavior of gas particles, allowing scientists to predict and calculate gas properties.
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2. Dalton's Law of Partial Pressures

Dalton's Law states that in a mixture of ideal gases, the total pressure is equal to the sum of the partial pressures of the individual gas components. Mathematically, we can write it as: \(P_{total} = P_1 + P_2 + \cdots + P_n\) Where \(P_{total}\) is the total pressure, and \(P_1, P_2, \cdots, P_n\) are the partial pressures of the individual gas components.
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3. Volumeless Gas Particles

The assumption of volumeless gas particles is important for the validity of Dalton's Law because it allows gas particles to be considered independently without worrying about their size. As the particles are assumed to be volumeless, their contribution to the total pressure is dependent only on the forces they exert on the container walls and not on the sizes of particles. This means each particle can be treated independently, and their partial pressures can be added up to get the total pressure.
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4. No Interactions Between Gas Particles

The assumption of no interaction between gas particles is also crucial to the validity of Dalton's Law because it prevents any interference between the particles that could affect their contribution to the total pressure. If gas particles attracted or repelled each other, their pressures wouldn't be independent, and they couldn't be added together as simply as in Dalton's Law.
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5. Conclusion

The assumptions of ideal gas particles being volumeless and having no interactions are crucial to the validity of Dalton's Law of Partial Pressures because they allow the pressure of individual gas particles to be added together without any complication due to their size or interaction. If the assumptions didn't hold, it would be much more difficult to accurately predict the total pressures of mixed gases using Dalton's Law.

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