A compressed gas cylinder contains \(1.00 \times 10^{3} \mathrm{g}\) argon gas. The pressure inside the cylinder is \(2050 .\) psi (pounds per square inch) at a temperature of \(18^{\circ} \mathrm{C}\) . How much gas remains in the cylinder if the pressure is decreased to 650 . psi at a temperature of $26^{\circ} \mathrm{C} ?$

Short Answer

Expert verified
There are approximately 359.14 grams of Argon gas remaining in the cylinder when the pressure is decreased to 650 psi at a temperature of 26°C.

Step by step solution

01

1. Convert mass of Argon to moles

To calculate the moles of Argon, we can use the equation: moles = mass / molar mass. The molar mass of Argon is 39.95 g/mol. Therefore: moles = \( \frac{1.00 \times 10^{3} \mathrm{g}}{39.95 \mathrm{g/mol}} \) moles = 25.03 mol
02

2. Convert psi to atm

We need to convert pressure from psi to atm, because the ideal gas law uses pressure in atm. The conversion factor is 1 atm = 14.696 psi. Therefore: Initial pressure = \( \frac{2050 \mathrm{psi}}{14.696 \mathrm{psi/atm}} \) = 139.58 atm Final pressure = \( \frac{650 \mathrm{psi}}{14.696 \mathrm{psi/atm}} \) = 44.24 atm
03

3. Convert Celsius to Kelvin

We need to convert temperature from degrees Celsius to Kelvin, because the ideal gas law uses temperature in Kelvin. To convert, add 273.15 to the Celsius temperature. Therefore: Initial Temperature = 18°C + 273.15 = 291.15 K Final Temperature = 26°C + 273.15 = 299.15 K
04

4. Calculate the volume of the cylinder

Using the ideal gas law, PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the gas constant (0.0821 \( \frac{\mathrm{L\cdot atm}}{\mathrm{mol\cdot K}} \)), and T is temperature, we can calculate the volume of the cylinder: V = \( \frac{nRT}{P} \) = \( \frac{(25.03 \mathrm{mol})(0.0821 \frac{\mathrm{L\cdot atm}}{\mathrm{mol\cdot K}})(291.15 \mathrm{K})}{139.58 \mathrm{atm}} \) V = 4.86 L
05

5. Calculate the moles of Argon remaining

We can use the ideal gas law again but with the final pressure and temperature values to determine the moles of Argon remaining in the cylinder: n_final = \( \frac{PV}{RT} \) = \( \frac{(44.24 \mathrm{atm})(4.86 \mathrm{L})}{(0.0821 \frac{\mathrm{L\cdot atm}}{\mathrm{mol\cdot K}})(299.15 \mathrm{K})} \) n_final = 8.99 mol
06

6. Convert moles of Argon back to grams

Finally, we can convert the moles of Argon remaining back to grams using the molar mass of Argon (39.95 g/mol): Mass remaining = (8.99 mol) (39.95 g/mol) = 359.14 g There are approximately 359.14 grams of Argon gas remaining in the cylinder.

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