Air bags are activated when a severe impact causes a steel ball to compress a spring and electrically ignite a detonator cap. This causes sodium azide \(\left(\mathrm{NaN}_{3}\right)\) to decompose explosively according to the following reaction: $$2 \mathrm{NaN}_{3}(s) \longrightarrow 2 \mathrm{Na}(s)+3 \mathrm{N}_{2}(g)$$ What mass of \(\mathrm{NaN}_{3}(s)\) must be reacted to inflate an air bag to 70.0 \(\mathrm{L}\) at STP?

Short Answer

Expert verified
To find the mass of sodium azide (NaN3) required to inflate an air bag to 70.0 L at STP, follow these steps: 1. Calculate the moles of N2 gas needed using the Ideal Gas Law: \(n(N_2) = \frac{PV}{RT} = \frac{(1\text{ atm})(70.0\text{ L})}{(0.08206\text{ L atm/mol K})(273.15\text{ K})}\) 2. Determine the moles of NaN3 required using stoichiometry: \(n(\mathrm{NaN}_3) = (n(N_2))\left(\frac{2\text{ mol NaN}_3}{3\text{ mol }N_2}\right)\) 3. Convert moles of NaN3 to mass using molar mass (65.01 g/mol): \(\text{mass}(\mathrm{NaN}_3) = n(\mathrm{NaN}_3) \times \text{molar mass}(\mathrm{NaN}_3)\) After completing these steps, you will find the mass of sodium azide needed to inflate the air bag to 70.0 L at STP.

Step by step solution

01

Determine moles of N2 gas to be generated

First, we must calculate the number of moles of N2 gas that need to be generated to fill the airbag of 70.0 L at STP. We'll use the Ideal Gas Law formula: PV = nRT where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature. Rearrange the formula to solve for n: n = PV / RT Given that at STP, P = 1 atm and T = 273.15 K, and using the ideal gas constant R = 0.08206 L atm/mol K, we can calculate the moles of N2 gas: n(N2) = (1 atm)(70.0 L) / (0.08206 L atm/mol K)(273.15 K)
02

Calculate moles of NaN3

Now that we have the number of moles of N2 gas required, we must determine the number of moles of NaN3 that need to be reacted according to the balanced chemical equation: $$2 \mathrm{NaN}_{3}(s) \longrightarrow 2 \mathrm{Na}(s)+3 \mathrm{N}_{2}(g)$$ Use stoichiometry to calculate the moles of NaN3 needed: n(NaN3) = (n(N2))(2 mol NaN3 / 3 mol N2)
03

Convert moles of NaN3 to mass

Now that we have the moles of NaN3 required, we need to convert it to mass. Use the molar mass of NaN3, which is: Molar mass of NaN3 = 22.99 g/mol (Na) + 14.01 g/mol (N) * 3 = 65.01 g/mol Determine the mass of NaN3 by multiplying the moles of NaN3 by its molar mass: mass(NaN3) = n(NaN3) * molar mass(NaN3) This will give you the mass of sodium azide required to inflate the airbag to 70.0 L at STP.

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Most popular questions from this chapter

As \(\mathrm{NH}_{3}(g)\) is decomposed into nitrogen gas and hydrogen gas at constant pressure and temperature, the volume of the product gases collected is twice the volume of \(\mathrm{NH}_{3}\) reacted. Explain. As \(\mathrm{NH}_{3}(g)\) is decomposed into nitrogen gas and hydrogen gas at constant volume and temperature, the total pressure increases by some factor. Why the increase in pressure and by what factor does the total pressure increase when reactants are completely converted into products? How do the partial pressures of the product gases compare to each other and to the initial pressure of \(\mathrm{NH}_{3}?\)

A 2.00 -L sample of \(\mathrm{O}_{2}(g)\) was collected over water at a total pressure of 785 torr and \(25^{\circ} \mathrm{C}\) . When the \(\mathrm{O}_{2}(g)\) was dried (water vapor removed), the gas had a volume of 1.94 \(\mathrm{L}\) at \(25^{\circ} \mathrm{C}\) and 785 torr. Calculate the vapor pressure of water at \(25^{\circ} \mathrm{C}.\)

Cyclopropane, a gas that when mixed with oxygen is used as a general anesthetic, is composed of 85.7\(\% \mathrm{C}\) and 14.3\(\% \mathrm{H}\) by mass. If the density of cyclopropane is 1.88 \(\mathrm{g} / \mathrm{L}\) at STP, what is the molecular formula of cyclopropane?

In Example 5.11 of the text, the molar volume of \(\mathrm{N}_{2}(g)\) at \(\mathrm{STP}\) is given as 22.42 \(\mathrm{Lmol} \mathrm{N}_{2} .\) How is this number calculated? How does the molar volume of He(g) at \(\mathrm{STP}\) compare to the molar volume of \(\mathrm{N}_{2}(g)\) at \(\mathrm{STP}\) (assuming ideal gas behavior)? Is the molar volume of \(\mathrm{N}_{2}(g)\) at 1.000 atm and \(25.0^{\circ} \mathrm{C}\) equal to, less than, or greater than 22.42 \(\mathrm{L} / \mathrm{mol} ?\) Explain. Is the molar volume of \(\mathrm{N}_{2}(g)\) collected over water at a total pressure of 1.000 \(\mathrm{atm}\) and \(0.0^{\circ} \mathrm{C}\) equal to, less than, or greater than 22.42 \(\mathrm{L} / \mathrm{mol}\) ? Explain.

Consider three identical flasks filled with different gases. Flask \(\mathrm{A} : \mathrm{CO}\) at 760 torr and \(0^{\circ} \mathrm{C}\) Flask \(\mathrm{B} : \mathrm{N}_{2}\) at 250 torr and \(0^{\circ} \mathrm{C}\) Flask \(\mathrm{C} : \mathrm{H}_{2}\) at 100 torr and \(0^{\circ} \mathrm{C}\) a. In which flask will the molecules have the greatest average kinetic energy? b. In which flask will the molecules have the greatest average velocity?

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