Chapter 6: Problem 25
Why is it a good idea to rinse your thermos bottle with hot water before filling it with hot coffee?
Chapter 6: Problem 25
Why is it a good idea to rinse your thermos bottle with hot water before filling it with hot coffee?
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Get started for freeCalculate \(\Delta E\) for each of the following. a. \(q=-47 \mathrm{kJ}, w=+88 \mathrm{kJ}\) b. \(q=+82 \mathrm{kJ}, w=-47 \mathrm{kJ}\) c. \(q=+47 \mathrm{kJ}, w=0\) d. In which of these cases do the surroundings do work on the system?
Given the following data $$ \begin{aligned} \mathrm{P}_{4}(s)+6 \mathrm{Cl}_{2}(g) \longrightarrow 4 \mathrm{PCl}_{3}(g) & \Delta H=-1225.6 \mathrm{kJ} \\ \mathrm{P}_{4}(s)+5 \mathrm{O}_{2}(g) \longrightarrow \mathrm{P}_{4} \mathrm{O}_{10}(s) & \Delta H=-2967.3 \mathrm{kJ} \end{aligned} $$ $$ \begin{array}{cc}{\mathrm{PCl}_{3}(g)+\mathrm{Cl}_{2}(g) \longrightarrow \mathrm{PCl}_{5}(g)} & {\Delta H=-84.2 \mathrm{kJ}} \\\ {\mathrm{PCl}_{3}(g)+\frac{1}{2} \mathrm{O}_{2}(g) \longrightarrow \mathrm{Cl}_{3} \mathrm{PO}(g)} & {\Delta H=-285.7 \mathrm{kJ}}\end{array} $$ calculate \(\Delta H\) for the reaction $$ \mathrm{P}_{4} \mathrm{O}_{10}(s)+6 \mathrm{PCl}_{5}(g) \longrightarrow 10 \mathrm{Cl}_{3} \mathrm{PO}(g) $$
Consider a balloon filled with helium at the following conditions. $$ \begin{array}{l}{313 \mathrm{g} \mathrm{He}} \\ {1.00 \mathrm{atm}} \\ {1910 . \mathrm{L}} \\ {\text { Molar Heat Capacity }=20.8 \mathrm{J} / \mathrm{C} \cdot \mathrm{mol}}\end{array} $$ The temperature of this balloon is decreased by \(41.6^{\circ} \mathrm{C}\) as the volume decreases to \(1643 \mathrm{L},\) with the pressure remaining constant. Determine \(q, w,\) and $\Delta E(\text { in } \mathrm{kJ} \text { ) for the compression of }$ the balloon.
Assume that \(4.19 \times 10^{6} \mathrm{kJ}\) of energy is needed to heat a home. If this energy is derived from the combustion of methane \(\left(\mathrm{CH}_{4}\right),\) what volume of methane, measured at STP, must be burned? $\left(\Delta H_{\text { combustion }}^{\circ} \text { for } \mathrm{CH}_{4}=-891 \mathrm{kJ} / \mathrm{mol}\right)$
A gas absorbs 45 kJ of heat and does 29 kJ of work. Calculate \(\Delta E .\)
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