Combustion reactions involve reacting a substance with oxygen. When compounds containing carbon and hydrogen are combusted, carbon dioxide and water are the products. Using the enthalpies of combustion for $\mathrm{C}_{4} \mathrm{H}_{4}(-2341 \mathrm{kJ} / \mathrm{mol}), \mathrm{C}_{4} \mathrm{H}_{8}\( \)(-2755 \mathrm{kJ} / \mathrm{mol}),\( and \)\mathrm{H}_{2}(-286 \mathrm{kJ} / \mathrm{mol}),\( calculate \)\Delta H$ for the reaction $$ \mathrm{C}_{4} \mathrm{H}_{4}(g)+2 \mathrm{H}_{2}(g) \longrightarrow \mathrm{C}_{4} \mathrm{H}_{8}(g) $$

Short Answer

Expert verified
The enthalpy change for the given reaction, \(\mathrm{C}_{4} \mathrm{H}_{4}(g)+2 \mathrm{H}_{2}(g) \longrightarrow \mathrm{C}_{4} \mathrm{H}_{8}(g),\) is \(\Delta H = -158\ \mathrm{kJ/mol}\).

Step by step solution

01

Write the combustion reactions for the given compounds

We are given the enthalpies of combustion for C4H4, C4H8, and H2. Let's write their combustion reactions with the enthalpy values: $$ \mathrm{C}_{4} \mathrm{H}_{4}(g) + 4\mathrm{O}_{2}(g) \longrightarrow 4\mathrm{CO}_{2}(g) + 2\mathrm{H}_{2}\mathrm{O}(l) \quad \Delta H_{1} = -2341\ \mathrm{kJ/mol} $$ $$ \mathrm{C}_{4} \mathrm{H}_{8}(g) + 6\mathrm{O}_{2}(g) \longrightarrow 4\mathrm{CO}_{2}(g) + 4\mathrm{H}_{2}\mathrm{O}(l) \quad \Delta H_{2} = -2755\ \mathrm{kJ/mol} $$ $$ \mathrm{H}_{2}(g) + \frac{1}{2}\mathrm{O}_{2}(g) \longrightarrow \mathrm{H}_{2}\mathrm{O}(l) \quad \Delta H_{3} = -286\ \mathrm{kJ/mol} $$
02

Manipulate the combustion reactions to obtain the target reaction

Now, we need to manipulate these combustion reactions in such a way that when we add them up, we get our target reaction, which is: $$ \mathrm{C}_{4} \mathrm{H}_{4}(g)+2 \mathrm{H}_{2}(g) \longrightarrow \mathrm{C}_{4} \mathrm{H}_{8}(g) $$ First, we reverse the second reaction for C4H8: $$ 4\mathrm{CO}_{2}(g) + 4\mathrm{H}_{2}\mathrm{O}(l) \longrightarrow \mathrm{C}_{4} \mathrm{H}_{8}(g) + 6\mathrm{O}_{2}(g) \quad \Delta H_{2}^{'} = 2755\ \mathrm{kJ/mol} $$ Then, we multiply the third reaction (for H2) by 2: $$ 2\mathrm{H}_{2}(g) + \mathrm{O}_{2}(g) \longrightarrow 2\mathrm{H}_{2}\mathrm{O}(l) \quad \Delta H_{3}^{'} = -572\ \mathrm{kJ/mol} $$
03

Add the manipulated reactions to get the target reaction and calculate \(\Delta H\)

Now we add the first reaction and the manipulated reactions for the second and third reactions. Notice that some terms will cancel out, and we'll be left with our target reaction: $$ \begin{aligned} \mathrm{C}_{4} \mathrm{H}_{4}(g) &+4 \mathrm{O}_{2}(g)+4 \mathrm{CO}_{2}(g)+4 \mathrm{H}_{2} \mathrm{O}(l)+2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow \\ &\quad 4 \mathrm{CO}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(l)+\mathrm{C}_{4} \mathrm{H}_{8}(g)+6 \mathrm{O}_{2}(g) \end{aligned} $$ The target reaction is obtained after canceling out common terms on both sides: $$ \mathrm{C}_{4} \mathrm{H}_{4}(g)+2 \mathrm{H}_{2}(g) \longrightarrow \mathrm{C}_{4} \mathrm{H}_{8}(g) $$ Now we can find the enthalpy change \(\Delta H\) for the target reaction by adding the manipulated enthalpy values: $$ \Delta H = \Delta H_{1} + \Delta H_{2}^{'} + \Delta H_{3}^{'} = (-2341) + 2755 + (-572) = -158\ \mathrm{kJ/mol} $$ So, the enthalpy change for the given reaction is \(\Delta H = -158\ \mathrm{kJ/mol}\).

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Most popular questions from this chapter

Some automobiles and buses have been equipped to burn propane \(\left(\mathrm{C}_{3} \mathrm{H}_{8}\right) .\) Compare the amounts of energy that can be obtained per gram of \(\mathrm{C}_{3} \mathrm{H}_{8}(g)\) and per gram of gasoline, assuming that gasoline is pure octane, $\mathrm{C}_{8} \mathrm{H}_{18}(l) .\( See Example \)6.11 .$ ) Look up the boiling point of propane. What disadvantages are there to using propane instead of gasoline as a fuel?

The enthalpy change for the reaction $$ \mathrm{CH}_{4}(g)+2 \mathrm{O}_{2}(g) \longrightarrow \mathrm{CO}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(l) $$ is \(-891 \mathrm{kJ}\) for the reaction as written. a. What quantity of heat is released for each mole of water formed? b. What quantity of heat is released for each mole of oxygen reacted?

The enthalpy of neutralization for the reaction of a strong acid with a strong base is \(-56 \mathrm{kJ} / \mathrm{mol}\) water produced. How much energy will be released when 200.0 \(\mathrm{mL}\) of 0.400 \(\mathrm{M} \mathrm{HNO}_{3}\) is mixed with 150.0 \(\mathrm{mL}\) of 0.500 \(\mathrm{M} \mathrm{KOH}\) ?

For the process $\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2} \mathrm{O}(g)\( at 298 \)\mathrm{K}\( and \)1.0 \mathrm{atm},\( \)\Delta H$ is more positive than \(\Delta E\) by 2.5 \(\mathrm{kJ} / \mathrm{mol}\) . What does the 2.5 \(\mathrm{kJ} / \mathrm{mol}\) quantity represent?

In a coffee-cup calorimeter, 150.0 \(\mathrm{mL}\) of 0.50 \(\mathrm{M}\) HCl is added to 50.0 \(\mathrm{mL}\) of 1.00 \(\mathrm{M} \mathrm{NaOH}\) to make 200.0 \(\mathrm{g}\) solution at an initial temperature of \(48.2^{\circ} \mathrm{C}\) . If the enthalpy of neutralization for the reaction between a strong acid and a strong base is \(-56 \mathrm{kJ} / \mathrm{mol}\) , calculate the final temperature of the calorimeter contents. Assume the specific heat capacity of the solution is 4.184 \(\mathrm{J} /^{\circ} \mathrm{C} \cdot \mathrm{g}\) and assume no heat loss to the surroundings.

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