One of the visible lines in the hydrogen emission spectrum corresponds to the \(n=6\) to \(n=2\) electronic transition. What color light is this transition? See Exercise 150 .

Short Answer

Expert verified
The color of light corresponding to the electronic transition from n=6 to n=2 in the hydrogen emission spectrum is violet. This result is obtained by calculating the wavelength of the light emitted during the transition using the Rydberg formula, which is found to be approximately \(410.3 \mathrm{nm}\), and looking up the color corresponding to this wavelength.

Step by step solution

01

Understanding the Rydberg formula

The Rydberg formula is used to calculate the wavelength of the light emitted due to electronic transitions in the hydrogen atom. The formula is given by: \( \dfrac{1}{\lambda} = R_{H} \left(\dfrac{1}{n_{1}^{2}} - \dfrac{1}{n_{2}^{2}}\right) \) Where: - \( \lambda \) is the wavelength of the light emitted, - \( R_{H} \) is the Rydberg constant for hydrogen, approximately equal to \( 1.097 \times 10^{7} \mathrm{m}^{-1} \), - \( n_{1} \) and \( n_{2} \) are the initial and final energy levels, respectively. In this case, we have the transitions from \( n_{1} = 6 \) to \( n_{2} = 2 \).
02

Calculate the wavelength

Using the Rydberg formula, we can calculate the wavelength of the light emitted during the transition from n=6 to n=2. \( \dfrac{1}{\lambda} = R_{H} \left(\dfrac{1}{2^{2}} - \dfrac{1}{6^{2}}\right) \) |Plug in the values and solve for \( \lambda \). \( \dfrac{1}{\lambda} = 1.097 \times 10^{7} \mathrm{m}^{-1} \left(\dfrac{1}{4} - \dfrac{1}{36}\right) \) \( \dfrac{1}{\lambda} = 1.097 \times 10^{7} \mathrm{m}^{-1} \left(\dfrac{32}{144}\right) \) \( \dfrac{1}{\lambda} = 1.097 \times 10^{7} \mathrm{m}^{-1} \times \dfrac{8}{36} \) Now, find \( \lambda \) by taking the inverse: \( \lambda = \dfrac{36}{1.097 \times 10^{7} \mathrm{m}^{-1} \times 8} \) \( \lambda \approx 4.103 \times 10^{-7} \mathrm{m} \) \( \lambda \approx 410.3 \mathrm{nm} \)
03

Determine the color of the light

The color of the light can be determined by looking up the wavelength in a table of visible light colors or using an online tool. The wavelength of \( 410.3 \mathrm{nm} \) corresponds to the color violet, which lies around spectral range (400nm - 450nm). Therefore, the color of the light emitted during the transition from n=6 to n=2 is violet.

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Most popular questions from this chapter

One of the emission spectral lines for \(\mathrm{Be}^{3+}\) has a wavelength of 253.4 \(\mathrm{nm}\) for an electronic transition that begins in the state with \(n=5 .\) What is the principal quantum number of the lower-energy state corresponding to this emission? (Hint: The Bohr model can be applied to one- electron ions. Don't forget the \(Z\) factor: \(Z=\) nuclear charge \(=\) atomic number.)

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