Chapter 7: Problem 18
What is meant by an orbital?
Chapter 7: Problem 18
What is meant by an orbital?
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Get started for freeIn the ground state of mercury, Hg, a. how many electrons occupy atomic orbitals with \(n=3 ?\) b. how many electrons occupy \(d\) atomic orbitals? c. how many electrons occupy \(p_{z}\) atomic orbitals? d. how many electrons have spin "up" " \(\left(m_{s}=+\frac{1}{2}\right) ?\)
For each of the following pairs of elements $$(\mathrm{C} \text { and } \mathrm{N}) \quad(\text { Ar and Br })$$ pick the atom with a. more favorable (exothermic) electron affinity. b. higher ionization energy. c. larger size.
A carbon-oxygen double bond in a certain organic molecule absorbs radiation that has a frequency of \(6.0 \times 10^{13} \mathrm{s}^{-1}\) . a. What is the wavelength of this radiation? b. To what region of the spectrum does this radiation belong? c. What is the energy of this radiation per photon? per mole of photons? d. A carbon-oxygen bond in a different molecule absorbs radiation with frequency equal to \(5.4 \times 10^{13} \mathrm{s}^{-1} .\) Is this radiation more or less energetic?
Three elements have the electron configurations 1\(s^{2} 2^{2} 2 p^{6} 3 s^{2}\) 1\(s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{4}\) , and 1$s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{2} .$ The first ionization energies of these elements (not in the same order) are 0.590 , 0.999, and 0.738 MJ/mol. The atomic radii are 104, 160, and 197 pm. Identify the three elements, and match the appropriate values of ionization energy and atomic radius to each configuration. Complete the following table with the correct information.
Photogray lenses incorporate small amounts of silver chloride in the glass of the lens. When light hits the AgCl particles, the following reaction occurs: $$\mathrm{AgCl} \stackrel{h v}{\longrightarrow} \mathrm{Ag}+\mathrm{Cl}$$ The silver metal that is formed causes the lenses to darken. The enthalpy change for this reaction is \(3.10 \times 10^{2} \mathrm{kJ} / \mathrm{mol}\) . Assuming all this energy must be supplied by light, what is the maximum wavelength of light that can cause this reaction?
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