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Chapter 7: Problem 40

Scientists use emission spectra to confirm the presence of an element in materials of unknown composition. Why is this possible?

Short Answer

Expert verified
In conclusion, identifying the presence of an element in materials of unknown composition using emission spectra is possible because each element has a unique atomic structure and emits specific wavelengths when excited. These distinct spectral signatures can be compared to known spectra, allowing scientists to confirm the presence of a particular element in the material.

Step by step solution

01

Introduction to Emission Spectra

Emission spectra refer to the distribution of electromagnetic radiation emitted by a substance when it is excited by an external source, like heat or electric discharge. Each element has a unique atomic structure, and when electrons in an atom are excited, they emit radiation in specific wavelengths, forming a pattern called an emission spectrum. This pattern can be thought of as the "fingerprint" of an element, which allows scientists to identify the presence of that element in a material.
02

Excitation of Electrons in Atoms

When an element in a material is subjected to high-energy excitation, its electrons absorb the energy and leap to higher energy levels (higher orbitals). This process is called electron excitation. The electrons are now in an unstable, excited state.
03

Relaxation of Electrons and Photon Emission

As the excited electrons relax, they return to their original, more stable energy levels (lower orbitals). During this relaxation process, the electrons release the energy they absorbed in the form of photons (particles of light). These photons correspond to specific wavelengths of electromagnetic radiation, depending on the difference in energy between the two levels involved.
04

Analysis of Emission Spectrum

The emitted photons create a spectrum of wavelengths of light, known as the emission spectrum. By analyzing this spectrum, scientists can identify the wavelengths at which the photons were emitted. Each element has a unique set of allowed transitions, determined by the atomic structure of the element. Therefore, the emission spectrum of an element serves as its unique signature.
05

Identifying the Presence of an Element

By comparing the observed emission spectrum of an unknown material with the known emission spectra of different elements, scientists can determine which elements are present in the material. If the observed spectrum matches the emission spectrum of a specific element, it confirms the presence of that element in the material. In conclusion, the ability to confirm the presence of an element in materials of unknown composition using emission spectra is possible because each element has unique atomic structure and emits various specific wavelengths when excited, creating a distinct spectral signature that can be identified and compared to known spectra.

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Most popular questions from this chapter

In the second row of the periodic table, Be, N, and Ne all have endothermic (unfavorable) electron affinities, whereas the other second-row elements have exothermic (favorable) electron affinities. Rationalize why Be, N, and Ne have unfavorable electron affinities.

Which of the following orbital designations are incorrect: \(1 s,\) $1 p, 7 d, 9 s, 3 f, 4 f, 2 d ?$

Does a photon of visible light $(\lambda \approx 400 \text { to } 700 \mathrm{nm})$ have sufficient energy to excite an electron in a hydrogen atom from the \(n=1\) to the \(n=5\) energy state? from the \(n=2\) to the \(n=6\) energy state?

Give a possible set of values of the four quantum numbers for the 4s and 3d electrons in titanium.

Give a possible set of values of the four quantum numbers for all the electrons in a boron atom and a nitrogen atom if each is in the ground state.
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